Dichlorido[(R,R)-N (1),N (1),N (2)-tribenzyl­cyclo­hexane-1,2-diamine-κ(2) N (1),N (2)]copper(II)

In the title compound, [CuCl(2)(C(27)H(32)N(2))], which bears a chiral diamine ligand, viz (R,R)-N,N,N′′- tribenzyl­cyclo­hexane-1,2-diamine, the Cu(II) ion is ligated by two N and two Cl atoms in a distorted square-planar geometry. The coordination of the ligands to the Cu(II) ion results in the fo...

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Detalles Bibliográficos
Autores principales: Nguyen, Quang Trung, Jeong, Jong Hwa
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979043/
https://www.ncbi.nlm.nih.gov/pubmed/21579047
http://dx.doi.org/10.1107/S1600536810014054
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author Nguyen, Quang Trung
Jeong, Jong Hwa
author_facet Nguyen, Quang Trung
Jeong, Jong Hwa
author_sort Nguyen, Quang Trung
collection PubMed
description In the title compound, [CuCl(2)(C(27)H(32)N(2))], which bears a chiral diamine ligand, viz (R,R)-N,N,N′′- tribenzyl­cyclo­hexane-1,2-diamine, the Cu(II) ion is ligated by two N and two Cl atoms in a distorted square-planar geometry. The coordination of the ligands to the Cu(II) ion results in the formation of a five-membered heterocyclic ring and a chiral center at the monosubstituted nitro­gen in an (S)-configuration. The catalytic capacity of the complex for the asymmetric nitro­aldol reaction is promising (49% ee).
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spelling pubmed-29790432010-12-30 Dichlorido[(R,R)-N (1),N (1),N (2)-tribenzyl­cyclo­hexane-1,2-diamine-κ(2) N (1),N (2)]copper(II) Nguyen, Quang Trung Jeong, Jong Hwa Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CuCl(2)(C(27)H(32)N(2))], which bears a chiral diamine ligand, viz (R,R)-N,N,N′′- tribenzyl­cyclo­hexane-1,2-diamine, the Cu(II) ion is ligated by two N and two Cl atoms in a distorted square-planar geometry. The coordination of the ligands to the Cu(II) ion results in the formation of a five-membered heterocyclic ring and a chiral center at the monosubstituted nitro­gen in an (S)-configuration. The catalytic capacity of the complex for the asymmetric nitro­aldol reaction is promising (49% ee). International Union of Crystallography 2010-04-24 /pmc/articles/PMC2979043/ /pubmed/21579047 http://dx.doi.org/10.1107/S1600536810014054 Text en © Nguyen and Jeong 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Nguyen, Quang Trung
Jeong, Jong Hwa
Dichlorido[(R,R)-N (1),N (1),N (2)-tribenzyl­cyclo­hexane-1,2-diamine-κ(2) N (1),N (2)]copper(II)
title Dichlorido[(R,R)-N (1),N (1),N (2)-tribenzyl­cyclo­hexane-1,2-diamine-κ(2) N (1),N (2)]copper(II)
title_full Dichlorido[(R,R)-N (1),N (1),N (2)-tribenzyl­cyclo­hexane-1,2-diamine-κ(2) N (1),N (2)]copper(II)
title_fullStr Dichlorido[(R,R)-N (1),N (1),N (2)-tribenzyl­cyclo­hexane-1,2-diamine-κ(2) N (1),N (2)]copper(II)
title_full_unstemmed Dichlorido[(R,R)-N (1),N (1),N (2)-tribenzyl­cyclo­hexane-1,2-diamine-κ(2) N (1),N (2)]copper(II)
title_short Dichlorido[(R,R)-N (1),N (1),N (2)-tribenzyl­cyclo­hexane-1,2-diamine-κ(2) N (1),N (2)]copper(II)
title_sort dichlorido[(r,r)-n (1),n (1),n (2)-tribenzyl­cyclo­hexane-1,2-diamine-κ(2) n (1),n (2)]copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979043/
https://www.ncbi.nlm.nih.gov/pubmed/21579047
http://dx.doi.org/10.1107/S1600536810014054
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AT jeongjonghwa dichloridorrn1n1n2tribenzylcyclohexane12diaminek2n1n2copperii

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