(5,10,15,20-Tetra­phenyl­porphyrinato-κ(4) N)cobalt(II)–18-crown-6 (1/1)

The asymmetric unit of the title compound, [Co(C(44)H(28)N(4))]·C(12)H(24)O(6), contains one half of a Co(II)(TPP) (TPP is tetra­phenyl­porphyrin) complex and one half of an 18-crown-6 mol­ecule of crystallization, both lying on inversion centers. The Co(II)(TPP) complex exhibits a nearly planar con...

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Autores principales: Mansour, Anissa, Belkhiria, Mohamed Salah, Daran, Jean-Claude, Nasri, Habib
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979047/
https://www.ncbi.nlm.nih.gov/pubmed/21579007
http://dx.doi.org/10.1107/S1600536810012080
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author Mansour, Anissa
Belkhiria, Mohamed Salah
Daran, Jean-Claude
Nasri, Habib
author_facet Mansour, Anissa
Belkhiria, Mohamed Salah
Daran, Jean-Claude
Nasri, Habib
author_sort Mansour, Anissa
collection PubMed
description The asymmetric unit of the title compound, [Co(C(44)H(28)N(4))]·C(12)H(24)O(6), contains one half of a Co(II)(TPP) (TPP is tetra­phenyl­porphyrin) complex and one half of an 18-crown-6 mol­ecule of crystallization, both lying on inversion centers. The Co(II)(TPP) complex exhibits a nearly planar conformation of the porphyrinate core [maximum deviation = 0.069 (2) Å] with an average Co—N distance of 1.971 (4) Å. The distance between the Co atom and the closest O atom of the 18-crown-6 mol­ecule is 2.533 (2) Å, indicating a short non-bonded contact between the Co atom and the crown ether mol­ecule. An ethyl­ene group of the 18-crown-6 mol­ecule is disordered over two sites with occupancies of 0.565 (7) and 0.435 (7).
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spelling pubmed-29790472010-12-30 (5,10,15,20-Tetra­phenyl­porphyrinato-κ(4) N)cobalt(II)–18-crown-6 (1/1) Mansour, Anissa Belkhiria, Mohamed Salah Daran, Jean-Claude Nasri, Habib Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Co(C(44)H(28)N(4))]·C(12)H(24)O(6), contains one half of a Co(II)(TPP) (TPP is tetra­phenyl­porphyrin) complex and one half of an 18-crown-6 mol­ecule of crystallization, both lying on inversion centers. The Co(II)(TPP) complex exhibits a nearly planar conformation of the porphyrinate core [maximum deviation = 0.069 (2) Å] with an average Co—N distance of 1.971 (4) Å. The distance between the Co atom and the closest O atom of the 18-crown-6 mol­ecule is 2.533 (2) Å, indicating a short non-bonded contact between the Co atom and the crown ether mol­ecule. An ethyl­ene group of the 18-crown-6 mol­ecule is disordered over two sites with occupancies of 0.565 (7) and 0.435 (7). International Union of Crystallography 2010-04-10 /pmc/articles/PMC2979047/ /pubmed/21579007 http://dx.doi.org/10.1107/S1600536810012080 Text en © Mansour et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Mansour, Anissa
Belkhiria, Mohamed Salah
Daran, Jean-Claude
Nasri, Habib
(5,10,15,20-Tetra­phenyl­porphyrinato-κ(4) N)cobalt(II)–18-crown-6 (1/1)
title (5,10,15,20-Tetra­phenyl­porphyrinato-κ(4) N)cobalt(II)–18-crown-6 (1/1)
title_full (5,10,15,20-Tetra­phenyl­porphyrinato-κ(4) N)cobalt(II)–18-crown-6 (1/1)
title_fullStr (5,10,15,20-Tetra­phenyl­porphyrinato-κ(4) N)cobalt(II)–18-crown-6 (1/1)
title_full_unstemmed (5,10,15,20-Tetra­phenyl­porphyrinato-κ(4) N)cobalt(II)–18-crown-6 (1/1)
title_short (5,10,15,20-Tetra­phenyl­porphyrinato-κ(4) N)cobalt(II)–18-crown-6 (1/1)
title_sort (5,10,15,20-tetra­phenyl­porphyrinato-κ(4) n)cobalt(ii)–18-crown-6 (1/1)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979047/
https://www.ncbi.nlm.nih.gov/pubmed/21579007
http://dx.doi.org/10.1107/S1600536810012080
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AT daranjeanclaude 5101520tetraphenylporphyrinatok4ncobaltii18crown611
AT nasrihabib 5101520tetraphenylporphyrinatok4ncobaltii18crown611

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