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Aqua(1H-benzimidazole-κN (3))(pyridine-2,6-dicarboxylato-κ(3) O (2),N,O (6))copper(II) 0.75-hydrate
The title complex, [Cu(C(7)H(3)NO(4))(C(7)H(6)N(2))(H(2)O)]·0.75H(2)O, consists of discrete monomeric units. The Cu(II) atom is coordinated by two carboxylate O atoms and the N atom from a dipicolinate unit and by an N atom from a benzimidazole ligand. The distorted square-pyramidal geometry is com...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979051/ https://www.ncbi.nlm.nih.gov/pubmed/21579026 http://dx.doi.org/10.1107/S160053681001353X |
| _version_ | 1782191331486990336 |
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| author | Dong, Gui-Ying Fan, Li-Hua Yang, Li-Xia Khan, Islam Ullah |
| author_facet | Dong, Gui-Ying Fan, Li-Hua Yang, Li-Xia Khan, Islam Ullah |
| author_sort | Dong, Gui-Ying |
| collection | PubMed |
| description | The title complex, [Cu(C(7)H(3)NO(4))(C(7)H(6)N(2))(H(2)O)]·0.75H(2)O, consists of discrete monomeric units. The Cu(II) atom is coordinated by two carboxylate O atoms and the N atom from a dipicolinate unit and by an N atom from a benzimidazole ligand. The distorted square-pyramidal geometry is completed by a longer axial bond to the O atom of a water molecule. The molecular structure and packing are stabilized by classical O—H⋯O and N—H⋯O hydrogen bonds, also including a disordered crystal water molecule. |
| format | Text |
| id | pubmed-2979051 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29790512010-12-30 Aqua(1H-benzimidazole-κN (3))(pyridine-2,6-dicarboxylato-κ(3) O (2),N,O (6))copper(II) 0.75-hydrate Dong, Gui-Ying Fan, Li-Hua Yang, Li-Xia Khan, Islam Ullah Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Cu(C(7)H(3)NO(4))(C(7)H(6)N(2))(H(2)O)]·0.75H(2)O, consists of discrete monomeric units. The Cu(II) atom is coordinated by two carboxylate O atoms and the N atom from a dipicolinate unit and by an N atom from a benzimidazole ligand. The distorted square-pyramidal geometry is completed by a longer axial bond to the O atom of a water molecule. The molecular structure and packing are stabilized by classical O—H⋯O and N—H⋯O hydrogen bonds, also including a disordered crystal water molecule. International Union of Crystallography 2010-04-17 /pmc/articles/PMC2979051/ /pubmed/21579026 http://dx.doi.org/10.1107/S160053681001353X Text en © Dong et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Dong, Gui-Ying Fan, Li-Hua Yang, Li-Xia Khan, Islam Ullah Aqua(1H-benzimidazole-κN (3))(pyridine-2,6-dicarboxylato-κ(3) O (2),N,O (6))copper(II) 0.75-hydrate |
| title | Aqua(1H-benzimidazole-κN
(3))(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))copper(II) 0.75-hydrate |
| title_full | Aqua(1H-benzimidazole-κN
(3))(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))copper(II) 0.75-hydrate |
| title_fullStr | Aqua(1H-benzimidazole-κN
(3))(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))copper(II) 0.75-hydrate |
| title_full_unstemmed | Aqua(1H-benzimidazole-κN
(3))(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))copper(II) 0.75-hydrate |
| title_short | Aqua(1H-benzimidazole-κN
(3))(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))copper(II) 0.75-hydrate |
| title_sort | aqua(1h-benzimidazole-κn
(3))(pyridine-2,6-dicarboxylato-κ(3)
o
(2),n,o
(6))copper(ii) 0.75-hydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979051/ https://www.ncbi.nlm.nih.gov/pubmed/21579026 http://dx.doi.org/10.1107/S160053681001353X |
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