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1-[(E)-(3,4-Dimethylisoxazol-5-yl)iminomethyl]-2-naphthol
The title Schiff base compound, C(16)H(14)N(2)O(2), has been synthesized by the reaction of 5-amino-3,4-dimethylisoxazole and 2-hydroxy-1-naphthaldehyde. The dihedral angle between the isoxazole ring and the napthyl ring system is 3.29 (7)°. The molecule adopts an E configuration about the centra...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979054/ https://www.ncbi.nlm.nih.gov/pubmed/21579099 http://dx.doi.org/10.1107/S160053681001216X |
Sumario: | The title Schiff base compound, C(16)H(14)N(2)O(2), has been synthesized by the reaction of 5-amino-3,4-dimethylisoxazole and 2-hydroxy-1-naphthaldehyde. The dihedral angle between the isoxazole ring and the napthyl ring system is 3.29 (7)°. The molecule adopts an E configuration about the central C=N double bond. Intramolecular O—H⋯N hydrogen bonding generates an S(6) ring motif. In the crystal structure, π–π interactions are observed involving the isoxazole ring and the substituted benzene ring of the naphthyl unit, with centroid–centroid distances of 3.5200 (10) Å. |
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