1-[(E)-(3,4-Dimethyl­isoxazol-5-yl)imino­meth­yl]-2-naphthol

The title Schiff base compound, C(16)H(14)N(2)O(2), has been synthesized by the reaction of 5-amino-3,4-dimethyl­isoxazole and 2-hydr­oxy-1-naphthaldehyde. The dihedral angle between the isoxazole ring and the napthyl ring system is 3.29 (7)°. The mol­ecule adopts an E configuration about the centra...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Hemamalini, Madhukar, Asiri, Abdullah M., Khan, Salman A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979054/
https://www.ncbi.nlm.nih.gov/pubmed/21579099
http://dx.doi.org/10.1107/S160053681001216X
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author Fun, Hoong-Kun
Hemamalini, Madhukar
Asiri, Abdullah M.
Khan, Salman A.
author_facet Fun, Hoong-Kun
Hemamalini, Madhukar
Asiri, Abdullah M.
Khan, Salman A.
author_sort Fun, Hoong-Kun
collection PubMed
description The title Schiff base compound, C(16)H(14)N(2)O(2), has been synthesized by the reaction of 5-amino-3,4-dimethyl­isoxazole and 2-hydr­oxy-1-naphthaldehyde. The dihedral angle between the isoxazole ring and the napthyl ring system is 3.29 (7)°. The mol­ecule adopts an E configuration about the central C=N double bond. Intra­molecular O—H⋯N hydrogen bonding generates an S(6) ring motif. In the crystal structure, π–π inter­actions are observed involving the isoxazole ring and the substituted benzene ring of the naphthyl unit, with centroid–centroid distances of 3.5200 (10) Å.
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spelling pubmed-29790542010-12-30 1-[(E)-(3,4-Dimethyl­isoxazol-5-yl)imino­meth­yl]-2-naphthol Fun, Hoong-Kun Hemamalini, Madhukar Asiri, Abdullah M. Khan, Salman A. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title Schiff base compound, C(16)H(14)N(2)O(2), has been synthesized by the reaction of 5-amino-3,4-dimethyl­isoxazole and 2-hydr­oxy-1-naphthaldehyde. The dihedral angle between the isoxazole ring and the napthyl ring system is 3.29 (7)°. The mol­ecule adopts an E configuration about the central C=N double bond. Intra­molecular O—H⋯N hydrogen bonding generates an S(6) ring motif. In the crystal structure, π–π inter­actions are observed involving the isoxazole ring and the substituted benzene ring of the naphthyl unit, with centroid–centroid distances of 3.5200 (10) Å. International Union of Crystallography 2010-04-10 /pmc/articles/PMC2979054/ /pubmed/21579099 http://dx.doi.org/10.1107/S160053681001216X Text en © Fun et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Hemamalini, Madhukar
Asiri, Abdullah M.
Khan, Salman A.
1-[(E)-(3,4-Dimethyl­isoxazol-5-yl)imino­meth­yl]-2-naphthol
title 1-[(E)-(3,4-Dimethyl­isoxazol-5-yl)imino­meth­yl]-2-naphthol
title_full 1-[(E)-(3,4-Dimethyl­isoxazol-5-yl)imino­meth­yl]-2-naphthol
title_fullStr 1-[(E)-(3,4-Dimethyl­isoxazol-5-yl)imino­meth­yl]-2-naphthol
title_full_unstemmed 1-[(E)-(3,4-Dimethyl­isoxazol-5-yl)imino­meth­yl]-2-naphthol
title_short 1-[(E)-(3,4-Dimethyl­isoxazol-5-yl)imino­meth­yl]-2-naphthol
title_sort 1-[(e)-(3,4-dimethyl­isoxazol-5-yl)imino­meth­yl]-2-naphthol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979054/
https://www.ncbi.nlm.nih.gov/pubmed/21579099
http://dx.doi.org/10.1107/S160053681001216X
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AT hemamalinimadhukar 1e34dimethylisoxazol5yliminomethyl2naphthol
AT asiriabdullahm 1e34dimethylisoxazol5yliminomethyl2naphthol
AT khansalmana 1e34dimethylisoxazol5yliminomethyl2naphthol

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