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Di-n-butyl{4-hydroxy-N′-[(2-oxido-1-naphthyl-κO)methylene]benzohydrazidato-κ(2) O,N′}tin(IV)
The deprotonated Schiff base ligand in the title compound, [Sn(C(4)H(9))(2)(C(18)H(12)N(2)O(3))], O,N,O′-chelates to the Sn atom, which is five-coordinated in a cis-C(2)NO(2)Sn trigonal-bipyramidal environment. The apical sites are occupied by the O atoms [O—Sn—O = 155.2 (2)°]. The hydroxy group is...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979056/ https://www.ncbi.nlm.nih.gov/pubmed/21579053 http://dx.doi.org/10.1107/S1600536810014662 |
| _version_ | 1782191332662444032 |
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| author | Affan, Md. Abu Sam, Norrihan Ahmad, Fasihuddin Ng, Seik Weng |
| author_facet | Affan, Md. Abu Sam, Norrihan Ahmad, Fasihuddin Ng, Seik Weng |
| author_sort | Affan, Md. Abu |
| collection | PubMed |
| description | The deprotonated Schiff base ligand in the title compound, [Sn(C(4)H(9))(2)(C(18)H(12)N(2)O(3))], O,N,O′-chelates to the Sn atom, which is five-coordinated in a cis-C(2)NO(2)Sn trigonal-bipyramidal environment. The apical sites are occupied by the O atoms [O—Sn—O = 155.2 (2)°]. The hydroxy group is a hydrogen-bond donor to the two-coordinate N atom of an adjacent molecule, the hydrogen-bonding interaction giving rise to a helical chain running along the c axis. The carbon atoms of the butyl chains are equally disordered over two positions. |
| format | Text |
| id | pubmed-2979056 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29790562010-12-30 Di-n-butyl{4-hydroxy-N′-[(2-oxido-1-naphthyl-κO)methylene]benzohydrazidato-κ(2) O,N′}tin(IV) Affan, Md. Abu Sam, Norrihan Ahmad, Fasihuddin Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The deprotonated Schiff base ligand in the title compound, [Sn(C(4)H(9))(2)(C(18)H(12)N(2)O(3))], O,N,O′-chelates to the Sn atom, which is five-coordinated in a cis-C(2)NO(2)Sn trigonal-bipyramidal environment. The apical sites are occupied by the O atoms [O—Sn—O = 155.2 (2)°]. The hydroxy group is a hydrogen-bond donor to the two-coordinate N atom of an adjacent molecule, the hydrogen-bonding interaction giving rise to a helical chain running along the c axis. The carbon atoms of the butyl chains are equally disordered over two positions. International Union of Crystallography 2010-04-24 /pmc/articles/PMC2979056/ /pubmed/21579053 http://dx.doi.org/10.1107/S1600536810014662 Text en © Affan et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Affan, Md. Abu Sam, Norrihan Ahmad, Fasihuddin Ng, Seik Weng Di-n-butyl{4-hydroxy-N′-[(2-oxido-1-naphthyl-κO)methylene]benzohydrazidato-κ(2) O,N′}tin(IV) |
| title | Di-n-butyl{4-hydroxy-N′-[(2-oxido-1-naphthyl-κO)methylene]benzohydrazidato-κ(2)
O,N′}tin(IV) |
| title_full | Di-n-butyl{4-hydroxy-N′-[(2-oxido-1-naphthyl-κO)methylene]benzohydrazidato-κ(2)
O,N′}tin(IV) |
| title_fullStr | Di-n-butyl{4-hydroxy-N′-[(2-oxido-1-naphthyl-κO)methylene]benzohydrazidato-κ(2)
O,N′}tin(IV) |
| title_full_unstemmed | Di-n-butyl{4-hydroxy-N′-[(2-oxido-1-naphthyl-κO)methylene]benzohydrazidato-κ(2)
O,N′}tin(IV) |
| title_short | Di-n-butyl{4-hydroxy-N′-[(2-oxido-1-naphthyl-κO)methylene]benzohydrazidato-κ(2)
O,N′}tin(IV) |
| title_sort | di-n-butyl{4-hydroxy-n′-[(2-oxido-1-naphthyl-κo)methylene]benzohydrazidato-κ(2)
o,n′}tin(iv) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979056/ https://www.ncbi.nlm.nih.gov/pubmed/21579053 http://dx.doi.org/10.1107/S1600536810014662 |
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