3-[2-(4,4-Dimethyl-2,6-dioxocyclo­hexyl­idene)hydrazin­yl]benzonitrile

The title compound, C(15)H(15)N(3)O(2), contains benzonitrile and 4,4-dimethyl-2,6-dioxocyclo­hexyl­idene groups connected via a hydrazinyl group. The structure is in the hydrazone tautomeric form in the solid state. The benzonitrile and hydrazinyl groups (3-hydrazinylbenzonitrile) are essentially c...

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Detalles Bibliográficos
Autores principales: Çolak, Naki, Aksakal, Didem, Andaç, Ömer, Büyükgüngör, Orhan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979068/
https://www.ncbi.nlm.nih.gov/pubmed/21579208
http://dx.doi.org/10.1107/S1600536810013164
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author Çolak, Naki
Aksakal, Didem
Andaç, Ömer
Büyükgüngör, Orhan
author_facet Çolak, Naki
Aksakal, Didem
Andaç, Ömer
Büyükgüngör, Orhan
author_sort Çolak, Naki
collection PubMed
description The title compound, C(15)H(15)N(3)O(2), contains benzonitrile and 4,4-dimethyl-2,6-dioxocyclo­hexyl­idene groups connected via a hydrazinyl group. The structure is in the hydrazone tautomeric form in the solid state. The benzonitrile and hydrazinyl groups (3-hydrazinylbenzonitrile) are essentially coplanar with an r.m.s. deviation of 0.016 Å. Intra­molecular N—H⋯O hydrogen bonding helps to stabilize the mol­ecular structure, and weak inter­molecular C—H⋯O hydrogen bonding is present in the crystal structure.
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spelling pubmed-29790682010-12-30 3-[2-(4,4-Dimethyl-2,6-dioxocyclo­hexyl­idene)hydrazin­yl]benzonitrile Çolak, Naki Aksakal, Didem Andaç, Ömer Büyükgüngör, Orhan Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(15)N(3)O(2), contains benzonitrile and 4,4-dimethyl-2,6-dioxocyclo­hexyl­idene groups connected via a hydrazinyl group. The structure is in the hydrazone tautomeric form in the solid state. The benzonitrile and hydrazinyl groups (3-hydrazinylbenzonitrile) are essentially coplanar with an r.m.s. deviation of 0.016 Å. Intra­molecular N—H⋯O hydrogen bonding helps to stabilize the mol­ecular structure, and weak inter­molecular C—H⋯O hydrogen bonding is present in the crystal structure. International Union of Crystallography 2010-04-24 /pmc/articles/PMC2979068/ /pubmed/21579208 http://dx.doi.org/10.1107/S1600536810013164 Text en © Çolak et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Çolak, Naki
Aksakal, Didem
Andaç, Ömer
Büyükgüngör, Orhan
3-[2-(4,4-Dimethyl-2,6-dioxocyclo­hexyl­idene)hydrazin­yl]benzonitrile
title 3-[2-(4,4-Dimethyl-2,6-dioxocyclo­hexyl­idene)hydrazin­yl]benzonitrile
title_full 3-[2-(4,4-Dimethyl-2,6-dioxocyclo­hexyl­idene)hydrazin­yl]benzonitrile
title_fullStr 3-[2-(4,4-Dimethyl-2,6-dioxocyclo­hexyl­idene)hydrazin­yl]benzonitrile
title_full_unstemmed 3-[2-(4,4-Dimethyl-2,6-dioxocyclo­hexyl­idene)hydrazin­yl]benzonitrile
title_short 3-[2-(4,4-Dimethyl-2,6-dioxocyclo­hexyl­idene)hydrazin­yl]benzonitrile
title_sort 3-[2-(4,4-dimethyl-2,6-dioxocyclo­hexyl­idene)hydrazin­yl]benzonitrile
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979068/
https://www.ncbi.nlm.nih.gov/pubmed/21579208
http://dx.doi.org/10.1107/S1600536810013164
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AT andacomer 3244dimethyl26dioxocyclohexylidenehydrazinylbenzonitrile
AT buyukgungororhan 3244dimethyl26dioxocyclohexylidenehydrazinylbenzonitrile

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