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Undecacarbonyl-1κ(3) C,2κ(4) C,3κ(4) C-[tris(3-chlorophenyl)phosphine-1κP]-triangulo-triruthenium(0)
In the title triangulo-triruthenium compound, [Ru(3)(C(18)H(12)Cl(3)P)(CO)(11)], one equatorial carbonyl group has been substituted by the monodentate phosphine ligand, leaving one equatorial and two axial carbonyl substituents on the Ru atom. The remaining two Ru atoms each carry two equatorial and...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979078/ https://www.ncbi.nlm.nih.gov/pubmed/21579060 http://dx.doi.org/10.1107/S1600536810013826 |
| _version_ | 1782191338040590336 |
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| author | Shawkataly, Omar bin Pankhi, Mohd. Aslam A. Yeap, Chin Sing Fun, Hoong-Kun |
| author_facet | Shawkataly, Omar bin Pankhi, Mohd. Aslam A. Yeap, Chin Sing Fun, Hoong-Kun |
| author_sort | Shawkataly, Omar bin |
| collection | PubMed |
| description | In the title triangulo-triruthenium compound, [Ru(3)(C(18)H(12)Cl(3)P)(CO)(11)], one equatorial carbonyl group has been substituted by the monodentate phosphine ligand, leaving one equatorial and two axial carbonyl substituents on the Ru atom. The remaining two Ru atoms each carry two equatorial and two axial terminal carbonyl ligands. The three benzene rings make dihedral angles of 87.83 (17), 69.91 (17) and 68.26 (17)° with each other. In the crystal structure, molecules are linked into dimers by intermolecular C—H⋯O hydrogen bonds. The molecular structure is stabilized by an intramolecular C—H⋯O hydrogen bond. |
| format | Text |
| id | pubmed-2979078 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29790782010-12-30 Undecacarbonyl-1κ(3) C,2κ(4) C,3κ(4) C-[tris(3-chlorophenyl)phosphine-1κP]-triangulo-triruthenium(0) Shawkataly, Omar bin Pankhi, Mohd. Aslam A. Yeap, Chin Sing Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title triangulo-triruthenium compound, [Ru(3)(C(18)H(12)Cl(3)P)(CO)(11)], one equatorial carbonyl group has been substituted by the monodentate phosphine ligand, leaving one equatorial and two axial carbonyl substituents on the Ru atom. The remaining two Ru atoms each carry two equatorial and two axial terminal carbonyl ligands. The three benzene rings make dihedral angles of 87.83 (17), 69.91 (17) and 68.26 (17)° with each other. In the crystal structure, molecules are linked into dimers by intermolecular C—H⋯O hydrogen bonds. The molecular structure is stabilized by an intramolecular C—H⋯O hydrogen bond. International Union of Crystallography 2010-04-28 /pmc/articles/PMC2979078/ /pubmed/21579060 http://dx.doi.org/10.1107/S1600536810013826 Text en © Shawkataly et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Shawkataly, Omar bin Pankhi, Mohd. Aslam A. Yeap, Chin Sing Fun, Hoong-Kun Undecacarbonyl-1κ(3) C,2κ(4) C,3κ(4) C-[tris(3-chlorophenyl)phosphine-1κP]-triangulo-triruthenium(0) |
| title | Undecacarbonyl-1κ(3)
C,2κ(4)
C,3κ(4)
C-[tris(3-chlorophenyl)phosphine-1κP]-triangulo-triruthenium(0) |
| title_full | Undecacarbonyl-1κ(3)
C,2κ(4)
C,3κ(4)
C-[tris(3-chlorophenyl)phosphine-1κP]-triangulo-triruthenium(0) |
| title_fullStr | Undecacarbonyl-1κ(3)
C,2κ(4)
C,3κ(4)
C-[tris(3-chlorophenyl)phosphine-1κP]-triangulo-triruthenium(0) |
| title_full_unstemmed | Undecacarbonyl-1κ(3)
C,2κ(4)
C,3κ(4)
C-[tris(3-chlorophenyl)phosphine-1κP]-triangulo-triruthenium(0) |
| title_short | Undecacarbonyl-1κ(3)
C,2κ(4)
C,3κ(4)
C-[tris(3-chlorophenyl)phosphine-1κP]-triangulo-triruthenium(0) |
| title_sort | undecacarbonyl-1κ(3)
c,2κ(4)
c,3κ(4)
c-[tris(3-chlorophenyl)phosphine-1κp]-triangulo-triruthenium(0) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979078/ https://www.ncbi.nlm.nih.gov/pubmed/21579060 http://dx.doi.org/10.1107/S1600536810013826 |
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