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3-Aminobenzoic acid–1,2-bis(4-pyridyl)ethane (1/1)
The asymmetric unit of the title compound, C(12)H(12)N(2)·C(7)H(7)NO(2), contains two 3-aminobenzoic acid molecules and two 1,2-bis(4-pyridyl)ethane molecules. In the two 1,2-bis(4-pyridyl)ethane molecules, the dihedral angles between the pyridyl rings are 2.99 (9) and 46.78 (8)°. In the cry...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979085/ https://www.ncbi.nlm.nih.gov/pubmed/21579186 http://dx.doi.org/10.1107/S1600536810014261 |
Sumario: | The asymmetric unit of the title compound, C(12)H(12)N(2)·C(7)H(7)NO(2), contains two 3-aminobenzoic acid molecules and two 1,2-bis(4-pyridyl)ethane molecules. In the two 1,2-bis(4-pyridyl)ethane molecules, the dihedral angles between the pyridyl rings are 2.99 (9) and 46.78 (8)°. In the crystal, the molecules associate through amine and carboxyl group N—H⋯O=C interactions between one of the 3-aminobenzoic acid molecules and one of the 1,2-bis(4-pyridyl)ethane molecules, generating R (2) (2)(14) dimers, which are extended head-to-tail via amine and pyridine N—H⋯N hydrogen bonds. Intermolecular O—H⋯N, N—H⋯O, N—H⋯N and C—H⋯O hydrogen bonding are observed in the crystal structure. C—H⋯π and π–π stacking interactions [centroid–centroid distance = 3.9985 (10) Å] are also present. |
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