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3-Amino­benzoic acid–1,2-bis­(4-pyrid­yl)ethane (1/1)

The asymmetric unit of the title compound, C(12)H(12)N(2)·C(7)H(7)NO(2), contains two 3-amino­benzoic acid mol­ecules and two 1,2-bis­(4-pyrid­yl)ethane mol­ecules. In the two 1,2-bis­(4-pyrid­yl)ethane mol­ecules, the dihedral angles between the pyridyl rings are 2.99 (9) and 46.78 (8)°. In the cry...

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Detalles Bibliográficos
Autores principales: Shen, Fwu Ming, Lush, Shie Fu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979085/
https://www.ncbi.nlm.nih.gov/pubmed/21579186
http://dx.doi.org/10.1107/S1600536810014261
Descripción
Sumario:The asymmetric unit of the title compound, C(12)H(12)N(2)·C(7)H(7)NO(2), contains two 3-amino­benzoic acid mol­ecules and two 1,2-bis­(4-pyrid­yl)ethane mol­ecules. In the two 1,2-bis­(4-pyrid­yl)ethane mol­ecules, the dihedral angles between the pyridyl rings are 2.99 (9) and 46.78 (8)°. In the crystal, the mol­ecules associate through amine and carboxyl group N—H⋯O=C inter­actions between one of the 3-amino­benzoic acid mol­ecules and one of the 1,2-bis­(4-pyrid­yl)ethane mol­ecules, generating R (2) (2)(14) dimers, which are extended head-to-tail via amine and pyridine N—H⋯N hydrogen bonds. Inter­molecular O—H⋯N, N—H⋯O, N—H⋯N and C—H⋯O hydrogen bonding are observed in the crystal structure. C—H⋯π and π–π stacking inter­actions [centroid–centroid distance = 3.9985 (10) Å] are also present.