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Poly[diaqua­bis(μ(2)-5-carb­oxy-2-propyl-1H-imidazole-4-carboxyl­ato-κ(3) N (3),O (4):O (5))lead(II)]

In the title complex, [Pb(C(8)H(9)N(2)O(4))(2)(H(2)O)(2)](n), the eight-coordinate Pb(II) atom lies on a twofold rotation axis and adopts a slightly distorted square-anti­prismatic N(2)O(6) coordination geometry. The ligand donor atoms are the tertiary N atoms of the imidazole rings and the carboxyl...

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Detalles Bibliográficos
Autores principales: Chen, Xiang, Liu, Hai-Cheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979092/
https://www.ncbi.nlm.nih.gov/pubmed/21579031
http://dx.doi.org/10.1107/S1600536810013735
Descripción
Sumario:In the title complex, [Pb(C(8)H(9)N(2)O(4))(2)(H(2)O)(2)](n), the eight-coordinate Pb(II) atom lies on a twofold rotation axis and adopts a slightly distorted square-anti­prismatic N(2)O(6) coordination geometry. The ligand donor atoms are the tertiary N atoms of the imidazole rings and the carboxyl­ate O atoms of two chelating 5-carb­oxy-2-propyl-1H-imidazole-4-carboxyl­ate ligands, the carb­oxy O atoms of two additional imidazole ligands and two water O atoms. The carb­oxy O and the N,O-chelate systems also link adjacent Pb(II) atoms, forming a two-dimensional layer structure, with four individual Pb(II) atoms located at the corners of a square. These layers are further inter­connected by an extensive array of O—H⋯O and N—H⋯O hydrogen bonds into a three-dimensional network.