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Poly[diaquabis(μ(2)-5-carboxy-2-propyl-1H-imidazole-4-carboxylato-κ(3) N (3),O (4):O (5))lead(II)]
In the title complex, [Pb(C(8)H(9)N(2)O(4))(2)(H(2)O)(2)](n), the eight-coordinate Pb(II) atom lies on a twofold rotation axis and adopts a slightly distorted square-antiprismatic N(2)O(6) coordination geometry. The ligand donor atoms are the tertiary N atoms of the imidazole rings and the carboxyl...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979092/ https://www.ncbi.nlm.nih.gov/pubmed/21579031 http://dx.doi.org/10.1107/S1600536810013735 |
Sumario: | In the title complex, [Pb(C(8)H(9)N(2)O(4))(2)(H(2)O)(2)](n), the eight-coordinate Pb(II) atom lies on a twofold rotation axis and adopts a slightly distorted square-antiprismatic N(2)O(6) coordination geometry. The ligand donor atoms are the tertiary N atoms of the imidazole rings and the carboxylate O atoms of two chelating 5-carboxy-2-propyl-1H-imidazole-4-carboxylate ligands, the carboxy O atoms of two additional imidazole ligands and two water O atoms. The carboxy O and the N,O-chelate systems also link adjacent Pb(II) atoms, forming a two-dimensional layer structure, with four individual Pb(II) atoms located at the corners of a square. These layers are further interconnected by an extensive array of O—H⋯O and N—H⋯O hydrogen bonds into a three-dimensional network. |
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