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Poly[diaquabis(μ(2)-5-carboxy-2-propyl-1H-imidazole-4-carboxylato-κ(3) N (3),O (4):O (5))lead(II)]
In the title complex, [Pb(C(8)H(9)N(2)O(4))(2)(H(2)O)(2)](n), the eight-coordinate Pb(II) atom lies on a twofold rotation axis and adopts a slightly distorted square-antiprismatic N(2)O(6) coordination geometry. The ligand donor atoms are the tertiary N atoms of the imidazole rings and the carboxyl...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979092/ https://www.ncbi.nlm.nih.gov/pubmed/21579031 http://dx.doi.org/10.1107/S1600536810013735 |
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author | Chen, Xiang Liu, Hai-Cheng |
author_facet | Chen, Xiang Liu, Hai-Cheng |
author_sort | Chen, Xiang |
collection | PubMed |
description | In the title complex, [Pb(C(8)H(9)N(2)O(4))(2)(H(2)O)(2)](n), the eight-coordinate Pb(II) atom lies on a twofold rotation axis and adopts a slightly distorted square-antiprismatic N(2)O(6) coordination geometry. The ligand donor atoms are the tertiary N atoms of the imidazole rings and the carboxylate O atoms of two chelating 5-carboxy-2-propyl-1H-imidazole-4-carboxylate ligands, the carboxy O atoms of two additional imidazole ligands and two water O atoms. The carboxy O and the N,O-chelate systems also link adjacent Pb(II) atoms, forming a two-dimensional layer structure, with four individual Pb(II) atoms located at the corners of a square. These layers are further interconnected by an extensive array of O—H⋯O and N—H⋯O hydrogen bonds into a three-dimensional network. |
format | Text |
id | pubmed-2979092 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29790922010-12-30 Poly[diaquabis(μ(2)-5-carboxy-2-propyl-1H-imidazole-4-carboxylato-κ(3) N (3),O (4):O (5))lead(II)] Chen, Xiang Liu, Hai-Cheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Pb(C(8)H(9)N(2)O(4))(2)(H(2)O)(2)](n), the eight-coordinate Pb(II) atom lies on a twofold rotation axis and adopts a slightly distorted square-antiprismatic N(2)O(6) coordination geometry. The ligand donor atoms are the tertiary N atoms of the imidazole rings and the carboxylate O atoms of two chelating 5-carboxy-2-propyl-1H-imidazole-4-carboxylate ligands, the carboxy O atoms of two additional imidazole ligands and two water O atoms. The carboxy O and the N,O-chelate systems also link adjacent Pb(II) atoms, forming a two-dimensional layer structure, with four individual Pb(II) atoms located at the corners of a square. These layers are further interconnected by an extensive array of O—H⋯O and N—H⋯O hydrogen bonds into a three-dimensional network. International Union of Crystallography 2010-04-21 /pmc/articles/PMC2979092/ /pubmed/21579031 http://dx.doi.org/10.1107/S1600536810013735 Text en © Chen and Liu 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Chen, Xiang Liu, Hai-Cheng Poly[diaquabis(μ(2)-5-carboxy-2-propyl-1H-imidazole-4-carboxylato-κ(3) N (3),O (4):O (5))lead(II)] |
title | Poly[diaquabis(μ(2)-5-carboxy-2-propyl-1H-imidazole-4-carboxylato-κ(3)
N
(3),O
(4):O
(5))lead(II)] |
title_full | Poly[diaquabis(μ(2)-5-carboxy-2-propyl-1H-imidazole-4-carboxylato-κ(3)
N
(3),O
(4):O
(5))lead(II)] |
title_fullStr | Poly[diaquabis(μ(2)-5-carboxy-2-propyl-1H-imidazole-4-carboxylato-κ(3)
N
(3),O
(4):O
(5))lead(II)] |
title_full_unstemmed | Poly[diaquabis(μ(2)-5-carboxy-2-propyl-1H-imidazole-4-carboxylato-κ(3)
N
(3),O
(4):O
(5))lead(II)] |
title_short | Poly[diaquabis(μ(2)-5-carboxy-2-propyl-1H-imidazole-4-carboxylato-κ(3)
N
(3),O
(4):O
(5))lead(II)] |
title_sort | poly[diaquabis(μ(2)-5-carboxy-2-propyl-1h-imidazole-4-carboxylato-κ(3)
n
(3),o
(4):o
(5))lead(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979092/ https://www.ncbi.nlm.nih.gov/pubmed/21579031 http://dx.doi.org/10.1107/S1600536810013735 |
work_keys_str_mv | AT chenxiang polydiaquabism25carboxy2propyl1himidazole4carboxylatok3n3o4o5leadii AT liuhaicheng polydiaquabism25carboxy2propyl1himidazole4carboxylatok3n3o4o5leadii |