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Poly[diaqua­bis(μ(2)-5-carb­oxy-2-propyl-1H-imidazole-4-carboxyl­ato-κ(3) N (3),O (4):O (5))lead(II)]

In the title complex, [Pb(C(8)H(9)N(2)O(4))(2)(H(2)O)(2)](n), the eight-coordinate Pb(II) atom lies on a twofold rotation axis and adopts a slightly distorted square-anti­prismatic N(2)O(6) coordination geometry. The ligand donor atoms are the tertiary N atoms of the imidazole rings and the carboxyl...

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Detalles Bibliográficos
Autores principales: Chen, Xiang, Liu, Hai-Cheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979092/
https://www.ncbi.nlm.nih.gov/pubmed/21579031
http://dx.doi.org/10.1107/S1600536810013735
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author Chen, Xiang
Liu, Hai-Cheng
author_facet Chen, Xiang
Liu, Hai-Cheng
author_sort Chen, Xiang
collection PubMed
description In the title complex, [Pb(C(8)H(9)N(2)O(4))(2)(H(2)O)(2)](n), the eight-coordinate Pb(II) atom lies on a twofold rotation axis and adopts a slightly distorted square-anti­prismatic N(2)O(6) coordination geometry. The ligand donor atoms are the tertiary N atoms of the imidazole rings and the carboxyl­ate O atoms of two chelating 5-carb­oxy-2-propyl-1H-imidazole-4-carboxyl­ate ligands, the carb­oxy O atoms of two additional imidazole ligands and two water O atoms. The carb­oxy O and the N,O-chelate systems also link adjacent Pb(II) atoms, forming a two-dimensional layer structure, with four individual Pb(II) atoms located at the corners of a square. These layers are further inter­connected by an extensive array of O—H⋯O and N—H⋯O hydrogen bonds into a three-dimensional network.
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spelling pubmed-29790922010-12-30 Poly[diaqua­bis(μ(2)-5-carb­oxy-2-propyl-1H-imidazole-4-carboxyl­ato-κ(3) N (3),O (4):O (5))lead(II)] Chen, Xiang Liu, Hai-Cheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Pb(C(8)H(9)N(2)O(4))(2)(H(2)O)(2)](n), the eight-coordinate Pb(II) atom lies on a twofold rotation axis and adopts a slightly distorted square-anti­prismatic N(2)O(6) coordination geometry. The ligand donor atoms are the tertiary N atoms of the imidazole rings and the carboxyl­ate O atoms of two chelating 5-carb­oxy-2-propyl-1H-imidazole-4-carboxyl­ate ligands, the carb­oxy O atoms of two additional imidazole ligands and two water O atoms. The carb­oxy O and the N,O-chelate systems also link adjacent Pb(II) atoms, forming a two-dimensional layer structure, with four individual Pb(II) atoms located at the corners of a square. These layers are further inter­connected by an extensive array of O—H⋯O and N—H⋯O hydrogen bonds into a three-dimensional network. International Union of Crystallography 2010-04-21 /pmc/articles/PMC2979092/ /pubmed/21579031 http://dx.doi.org/10.1107/S1600536810013735 Text en © Chen and Liu 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chen, Xiang
Liu, Hai-Cheng
Poly[diaqua­bis(μ(2)-5-carb­oxy-2-propyl-1H-imidazole-4-carboxyl­ato-κ(3) N (3),O (4):O (5))lead(II)]
title Poly[diaqua­bis(μ(2)-5-carb­oxy-2-propyl-1H-imidazole-4-carboxyl­ato-κ(3) N (3),O (4):O (5))lead(II)]
title_full Poly[diaqua­bis(μ(2)-5-carb­oxy-2-propyl-1H-imidazole-4-carboxyl­ato-κ(3) N (3),O (4):O (5))lead(II)]
title_fullStr Poly[diaqua­bis(μ(2)-5-carb­oxy-2-propyl-1H-imidazole-4-carboxyl­ato-κ(3) N (3),O (4):O (5))lead(II)]
title_full_unstemmed Poly[diaqua­bis(μ(2)-5-carb­oxy-2-propyl-1H-imidazole-4-carboxyl­ato-κ(3) N (3),O (4):O (5))lead(II)]
title_short Poly[diaqua­bis(μ(2)-5-carb­oxy-2-propyl-1H-imidazole-4-carboxyl­ato-κ(3) N (3),O (4):O (5))lead(II)]
title_sort poly[diaqua­bis(μ(2)-5-carb­oxy-2-propyl-1h-imidazole-4-carboxyl­ato-κ(3) n (3),o (4):o (5))lead(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979092/
https://www.ncbi.nlm.nih.gov/pubmed/21579031
http://dx.doi.org/10.1107/S1600536810013735
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