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(2S*)-2-Ammonio-3-(1H-indol-3-yl)propionate pyridine-2,4-dicarboxylic acid ethanol solvate
In the title compound, C(11)H(12)N(2)O(2)·C(7)H(5)NO(4)·C(2)H(6)O, the (2S*)-2-amino-3-(1H-indol-3-yl)propionic acid is present in the zwitterionic form. In the crystal structure, 2-amino-3-(1H-indol-3-yl)propionic acid molecules and pyridine-2,4-dicarboxylic acid molecules are linked through str...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979096/ https://www.ncbi.nlm.nih.gov/pubmed/21579175 http://dx.doi.org/10.1107/S1600536810014017 |
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author | Di, Kai |
author_facet | Di, Kai |
author_sort | Di, Kai |
collection | PubMed |
description | In the title compound, C(11)H(12)N(2)O(2)·C(7)H(5)NO(4)·C(2)H(6)O, the (2S*)-2-amino-3-(1H-indol-3-yl)propionic acid is present in the zwitterionic form. In the crystal structure, 2-amino-3-(1H-indol-3-yl)propionic acid molecules and pyridine-2,4-dicarboxylic acid molecules are linked through strong intermolecular O—H⋯O and N—H⋯O hydrogen bonds, forming layers parallel to (100). The layers are linked through the ethanol molecules via somewhat weaker intermolecular O—H⋯O and N—H⋯O hydrogen bonds, forming thus a three-dimensional network. Weak C—H⋯O and N—H⋯N hydrogen bonding and π–π interactions between the aromatic rings are also present. |
format | Text |
id | pubmed-2979096 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29790962010-12-30 (2S*)-2-Ammonio-3-(1H-indol-3-yl)propionate pyridine-2,4-dicarboxylic acid ethanol solvate Di, Kai Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(11)H(12)N(2)O(2)·C(7)H(5)NO(4)·C(2)H(6)O, the (2S*)-2-amino-3-(1H-indol-3-yl)propionic acid is present in the zwitterionic form. In the crystal structure, 2-amino-3-(1H-indol-3-yl)propionic acid molecules and pyridine-2,4-dicarboxylic acid molecules are linked through strong intermolecular O—H⋯O and N—H⋯O hydrogen bonds, forming layers parallel to (100). The layers are linked through the ethanol molecules via somewhat weaker intermolecular O—H⋯O and N—H⋯O hydrogen bonds, forming thus a three-dimensional network. Weak C—H⋯O and N—H⋯N hydrogen bonding and π–π interactions between the aromatic rings are also present. International Union of Crystallography 2010-04-21 /pmc/articles/PMC2979096/ /pubmed/21579175 http://dx.doi.org/10.1107/S1600536810014017 Text en © Kai Di 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Di, Kai (2S*)-2-Ammonio-3-(1H-indol-3-yl)propionate pyridine-2,4-dicarboxylic acid ethanol solvate |
title | (2S*)-2-Ammonio-3-(1H-indol-3-yl)propionate pyridine-2,4-dicarboxylic acid ethanol solvate |
title_full | (2S*)-2-Ammonio-3-(1H-indol-3-yl)propionate pyridine-2,4-dicarboxylic acid ethanol solvate |
title_fullStr | (2S*)-2-Ammonio-3-(1H-indol-3-yl)propionate pyridine-2,4-dicarboxylic acid ethanol solvate |
title_full_unstemmed | (2S*)-2-Ammonio-3-(1H-indol-3-yl)propionate pyridine-2,4-dicarboxylic acid ethanol solvate |
title_short | (2S*)-2-Ammonio-3-(1H-indol-3-yl)propionate pyridine-2,4-dicarboxylic acid ethanol solvate |
title_sort | (2s*)-2-ammonio-3-(1h-indol-3-yl)propionate pyridine-2,4-dicarboxylic acid ethanol solvate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979096/ https://www.ncbi.nlm.nih.gov/pubmed/21579175 http://dx.doi.org/10.1107/S1600536810014017 |
work_keys_str_mv | AT dikai 2s2ammonio31hindol3ylpropionatepyridine24dicarboxylicacidethanolsolvate |