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(2S*)-2-Ammonio-3-(1H-indol-3-yl)propionate pyridine-2,4-dicarboxylic acid ethanol solvate

In the title compound, C(11)H(12)N(2)O(2)·C(7)H(5)NO(4)·C(2)H(6)O, the (2S*)-2-amino-3-(1H-indol-3-yl)propionic acid is present in the zwitterionic form. In the crystal structure, 2-amino-3-(1H-indol-3-yl)propionic acid mol­ecules and pyridine-2,4-dicarb­oxylic acid mol­ecules are linked through str...

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Detalles Bibliográficos
Autor principal: Di, Kai
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979096/
https://www.ncbi.nlm.nih.gov/pubmed/21579175
http://dx.doi.org/10.1107/S1600536810014017
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author Di, Kai
author_facet Di, Kai
author_sort Di, Kai
collection PubMed
description In the title compound, C(11)H(12)N(2)O(2)·C(7)H(5)NO(4)·C(2)H(6)O, the (2S*)-2-amino-3-(1H-indol-3-yl)propionic acid is present in the zwitterionic form. In the crystal structure, 2-amino-3-(1H-indol-3-yl)propionic acid mol­ecules and pyridine-2,4-dicarb­oxylic acid mol­ecules are linked through strong inter­molecular O—H⋯O and N—H⋯O hydrogen bonds, forming layers parallel to (100). The layers are linked through the ethanol mol­ecules via somewhat weaker inter­molecular O—H⋯O and N—H⋯O hydrogen bonds, forming thus a three-dimensional network. Weak C—H⋯O and N—H⋯N hydrogen bonding and π–π inter­actions between the aromatic rings are also present.
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spelling pubmed-29790962010-12-30 (2S*)-2-Ammonio-3-(1H-indol-3-yl)propionate pyridine-2,4-dicarboxylic acid ethanol solvate Di, Kai Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(11)H(12)N(2)O(2)·C(7)H(5)NO(4)·C(2)H(6)O, the (2S*)-2-amino-3-(1H-indol-3-yl)propionic acid is present in the zwitterionic form. In the crystal structure, 2-amino-3-(1H-indol-3-yl)propionic acid mol­ecules and pyridine-2,4-dicarb­oxylic acid mol­ecules are linked through strong inter­molecular O—H⋯O and N—H⋯O hydrogen bonds, forming layers parallel to (100). The layers are linked through the ethanol mol­ecules via somewhat weaker inter­molecular O—H⋯O and N—H⋯O hydrogen bonds, forming thus a three-dimensional network. Weak C—H⋯O and N—H⋯N hydrogen bonding and π–π inter­actions between the aromatic rings are also present. International Union of Crystallography 2010-04-21 /pmc/articles/PMC2979096/ /pubmed/21579175 http://dx.doi.org/10.1107/S1600536810014017 Text en © Kai Di 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Di, Kai
(2S*)-2-Ammonio-3-(1H-indol-3-yl)propionate pyridine-2,4-dicarboxylic acid ethanol solvate
title (2S*)-2-Ammonio-3-(1H-indol-3-yl)propionate pyridine-2,4-dicarboxylic acid ethanol solvate
title_full (2S*)-2-Ammonio-3-(1H-indol-3-yl)propionate pyridine-2,4-dicarboxylic acid ethanol solvate
title_fullStr (2S*)-2-Ammonio-3-(1H-indol-3-yl)propionate pyridine-2,4-dicarboxylic acid ethanol solvate
title_full_unstemmed (2S*)-2-Ammonio-3-(1H-indol-3-yl)propionate pyridine-2,4-dicarboxylic acid ethanol solvate
title_short (2S*)-2-Ammonio-3-(1H-indol-3-yl)propionate pyridine-2,4-dicarboxylic acid ethanol solvate
title_sort (2s*)-2-ammonio-3-(1h-indol-3-yl)propionate pyridine-2,4-dicarboxylic acid ethanol solvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979096/
https://www.ncbi.nlm.nih.gov/pubmed/21579175
http://dx.doi.org/10.1107/S1600536810014017
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