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Heptacarbonyl-1κ(3) C,2κ(4) C-(4-phenylpyridine-1κN)di-μ-phenyltellurido-1:2κ(4) Te:Te-dirhenium(I)
In the title complex, [Re(2)(C(6)H(5)Te)(2)(C(11)H(9)N)(CO)(7)], two Re atoms are coordinated in slightly distorted octahedral coordination environments and are bridged by two Te atoms, which are coordinated in trigonal-pyramidal environments. The torsion angle for the Te—Re—Te—Re sequence of atoms...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979103/ https://www.ncbi.nlm.nih.gov/pubmed/21579015 http://dx.doi.org/10.1107/S1600536810012389 |
| _version_ | 1782191344034250752 |
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| author | Vanitha, A. Muthukumaran, J. Krishna, R. Manimaran, Bala |
| author_facet | Vanitha, A. Muthukumaran, J. Krishna, R. Manimaran, Bala |
| author_sort | Vanitha, A. |
| collection | PubMed |
| description | In the title complex, [Re(2)(C(6)H(5)Te)(2)(C(11)H(9)N)(CO)(7)], two Re atoms are coordinated in slightly distorted octahedral coordination environments and are bridged by two Te atoms, which are coordinated in trigonal-pyramidal environments. The torsion angle for the Te—Re—Te—Re sequence of atoms is 17.06 (3)°. The crystal structure is stabilized by weak C—H⋯O and C—H⋯π interactions. In addition, there are Te⋯Te distances [4.0392 (12) Å] and O⋯O distances [2.902 (19) Å] which are shorter than the sum of the van der Waals radii for these atoms. A short intermolecular lone pair⋯π distance [C O⋯Cg = 3.31 (2) Å] is also observed. |
| format | Text |
| id | pubmed-2979103 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29791032010-12-30 Heptacarbonyl-1κ(3) C,2κ(4) C-(4-phenylpyridine-1κN)di-μ-phenyltellurido-1:2κ(4) Te:Te-dirhenium(I) Vanitha, A. Muthukumaran, J. Krishna, R. Manimaran, Bala Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Re(2)(C(6)H(5)Te)(2)(C(11)H(9)N)(CO)(7)], two Re atoms are coordinated in slightly distorted octahedral coordination environments and are bridged by two Te atoms, which are coordinated in trigonal-pyramidal environments. The torsion angle for the Te—Re—Te—Re sequence of atoms is 17.06 (3)°. The crystal structure is stabilized by weak C—H⋯O and C—H⋯π interactions. In addition, there are Te⋯Te distances [4.0392 (12) Å] and O⋯O distances [2.902 (19) Å] which are shorter than the sum of the van der Waals radii for these atoms. A short intermolecular lone pair⋯π distance [C O⋯Cg = 3.31 (2) Å] is also observed. International Union of Crystallography 2010-04-14 /pmc/articles/PMC2979103/ /pubmed/21579015 http://dx.doi.org/10.1107/S1600536810012389 Text en © Vanitha et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Vanitha, A. Muthukumaran, J. Krishna, R. Manimaran, Bala Heptacarbonyl-1κ(3) C,2κ(4) C-(4-phenylpyridine-1κN)di-μ-phenyltellurido-1:2κ(4) Te:Te-dirhenium(I) |
| title | Heptacarbonyl-1κ(3)
C,2κ(4)
C-(4-phenylpyridine-1κN)di-μ-phenyltellurido-1:2κ(4)
Te:Te-dirhenium(I) |
| title_full | Heptacarbonyl-1κ(3)
C,2κ(4)
C-(4-phenylpyridine-1κN)di-μ-phenyltellurido-1:2κ(4)
Te:Te-dirhenium(I) |
| title_fullStr | Heptacarbonyl-1κ(3)
C,2κ(4)
C-(4-phenylpyridine-1κN)di-μ-phenyltellurido-1:2κ(4)
Te:Te-dirhenium(I) |
| title_full_unstemmed | Heptacarbonyl-1κ(3)
C,2κ(4)
C-(4-phenylpyridine-1κN)di-μ-phenyltellurido-1:2κ(4)
Te:Te-dirhenium(I) |
| title_short | Heptacarbonyl-1κ(3)
C,2κ(4)
C-(4-phenylpyridine-1κN)di-μ-phenyltellurido-1:2κ(4)
Te:Te-dirhenium(I) |
| title_sort | heptacarbonyl-1κ(3)
c,2κ(4)
c-(4-phenylpyridine-1κn)di-μ-phenyltellurido-1:2κ(4)
te:te-dirhenium(i) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979103/ https://www.ncbi.nlm.nih.gov/pubmed/21579015 http://dx.doi.org/10.1107/S1600536810012389 |
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