4-(4-Pyrid­yl)pyridinium perchlorate methanol solvate

In the cation of the title hydrated molecular salt, C(10)H(9)N(2) (+)·ClO(4) (−)·CH(3)OH, the dihedral angle formed by the pyridine rings is 28.82 (15)°. The crystal structure is stabilized by inter­molecular N—H⋯O and O—H⋯N hydrogen bonds and π–π stacking inter­actions, with centroid-to-centroid di...

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Detalles Bibliográficos
Autores principales: Gao, Yu-Hua, Wu, De-Ming
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979109/
https://www.ncbi.nlm.nih.gov/pubmed/21579123
http://dx.doi.org/10.1107/S1600536810012985
Descripción
Sumario:In the cation of the title hydrated molecular salt, C(10)H(9)N(2) (+)·ClO(4) (−)·CH(3)OH, the dihedral angle formed by the pyridine rings is 28.82 (15)°. The crystal structure is stabilized by inter­molecular N—H⋯O and O—H⋯N hydrogen bonds and π–π stacking inter­actions, with centroid-to-centroid distances of 3.5913 (7) and 3.6526 (7) Å. Three O atoms of the perchlorate anion are disordered over two positions with refined occupancy factors of 0.649 (7):0.351 (7).

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