4-(4-Pyrid­yl)pyridinium perchlorate methanol solvate

In the cation of the title hydrated molecular salt, C(10)H(9)N(2) (+)·ClO(4) (−)·CH(3)OH, the dihedral angle formed by the pyridine rings is 28.82 (15)°. The crystal structure is stabilized by inter­molecular N—H⋯O and O—H⋯N hydrogen bonds and π–π stacking inter­actions, with centroid-to-centroid di...

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Detalles Bibliográficos
Autores principales: Gao, Yu-Hua, Wu, De-Ming
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979109/
https://www.ncbi.nlm.nih.gov/pubmed/21579123
http://dx.doi.org/10.1107/S1600536810012985
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author Gao, Yu-Hua
Wu, De-Ming
author_facet Gao, Yu-Hua
Wu, De-Ming
author_sort Gao, Yu-Hua
collection PubMed
description In the cation of the title hydrated molecular salt, C(10)H(9)N(2) (+)·ClO(4) (−)·CH(3)OH, the dihedral angle formed by the pyridine rings is 28.82 (15)°. The crystal structure is stabilized by inter­molecular N—H⋯O and O—H⋯N hydrogen bonds and π–π stacking inter­actions, with centroid-to-centroid distances of 3.5913 (7) and 3.6526 (7) Å. Three O atoms of the perchlorate anion are disordered over two positions with refined occupancy factors of 0.649 (7):0.351 (7).
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spelling pubmed-29791092010-12-30 4-(4-Pyrid­yl)pyridinium perchlorate methanol solvate Gao, Yu-Hua Wu, De-Ming Acta Crystallogr Sect E Struct Rep Online Organic Papers In the cation of the title hydrated molecular salt, C(10)H(9)N(2) (+)·ClO(4) (−)·CH(3)OH, the dihedral angle formed by the pyridine rings is 28.82 (15)°. The crystal structure is stabilized by inter­molecular N—H⋯O and O—H⋯N hydrogen bonds and π–π stacking inter­actions, with centroid-to-centroid distances of 3.5913 (7) and 3.6526 (7) Å. Three O atoms of the perchlorate anion are disordered over two positions with refined occupancy factors of 0.649 (7):0.351 (7). International Union of Crystallography 2010-04-14 /pmc/articles/PMC2979109/ /pubmed/21579123 http://dx.doi.org/10.1107/S1600536810012985 Text en © Gao and Wu 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gao, Yu-Hua
Wu, De-Ming
4-(4-Pyrid­yl)pyridinium perchlorate methanol solvate
title 4-(4-Pyrid­yl)pyridinium perchlorate methanol solvate
title_full 4-(4-Pyrid­yl)pyridinium perchlorate methanol solvate
title_fullStr 4-(4-Pyrid­yl)pyridinium perchlorate methanol solvate
title_full_unstemmed 4-(4-Pyrid­yl)pyridinium perchlorate methanol solvate
title_short 4-(4-Pyrid­yl)pyridinium perchlorate methanol solvate
title_sort 4-(4-pyrid­yl)pyridinium perchlorate methanol solvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979109/
https://www.ncbi.nlm.nih.gov/pubmed/21579123
http://dx.doi.org/10.1107/S1600536810012985
work_keys_str_mv AT gaoyuhua 44pyridylpyridiniumperchloratemethanolsolvate
AT wudeming 44pyridylpyridiniumperchloratemethanolsolvate

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