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catena-Poly[[(acetato-κ(2) O,O′)(methanol-κO)cadmium(II)]-μ-[1,2-bis(1H-benzimidazol-2-yl)ethane]-κ(2) N (3):N (3′)-[(acetato-κ(2) O,O′)(methanol-κO)cadmium(II)]-di-μ-chlorido]
In the title complex, [Cd(2)(CH(3)COO)(2)Cl(2)(C(16)H(14)N(4))(CH(3)OH)(2)](n), the Cd(II) atom is six-coordinated by one N atom from a centrosymmetric bridging 1,2-bis(2,2′-1H-benzimidazol-2-yl)ethane (bbe) ligand, two O atoms from a chelating acetate ligand, one O atom from a methanol molecule a...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979110/ https://www.ncbi.nlm.nih.gov/pubmed/21579058 http://dx.doi.org/10.1107/S1600536810014753 |
| _version_ | 1782191345709875200 |
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| author | Yang, Huai-Xia Zhang, Jun Ding, Ya-Nan Meng, Xiang-Ru |
| author_facet | Yang, Huai-Xia Zhang, Jun Ding, Ya-Nan Meng, Xiang-Ru |
| author_sort | Yang, Huai-Xia |
| collection | PubMed |
| description | In the title complex, [Cd(2)(CH(3)COO)(2)Cl(2)(C(16)H(14)N(4))(CH(3)OH)(2)](n), the Cd(II) atom is six-coordinated by one N atom from a centrosymmetric bridging 1,2-bis(2,2′-1H-benzimidazol-2-yl)ethane (bbe) ligand, two O atoms from a chelating acetate ligand, one O atom from a methanol molecule and two bridging Cl atoms in a distorted octahedral geometry. The Cd(II) atoms are connected alternately by the Cl atoms and bbe ligands, leading to a chain along [001]. These chains are further linked by O—H⋯O hydrogen bonds. Intrachain N—H⋯O hydrogen bonds are observed. |
| format | Text |
| id | pubmed-2979110 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29791102010-12-30 catena-Poly[[(acetato-κ(2) O,O′)(methanol-κO)cadmium(II)]-μ-[1,2-bis(1H-benzimidazol-2-yl)ethane]-κ(2) N (3):N (3′)-[(acetato-κ(2) O,O′)(methanol-κO)cadmium(II)]-di-μ-chlorido] Yang, Huai-Xia Zhang, Jun Ding, Ya-Nan Meng, Xiang-Ru Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cd(2)(CH(3)COO)(2)Cl(2)(C(16)H(14)N(4))(CH(3)OH)(2)](n), the Cd(II) atom is six-coordinated by one N atom from a centrosymmetric bridging 1,2-bis(2,2′-1H-benzimidazol-2-yl)ethane (bbe) ligand, two O atoms from a chelating acetate ligand, one O atom from a methanol molecule and two bridging Cl atoms in a distorted octahedral geometry. The Cd(II) atoms are connected alternately by the Cl atoms and bbe ligands, leading to a chain along [001]. These chains are further linked by O—H⋯O hydrogen bonds. Intrachain N—H⋯O hydrogen bonds are observed. International Union of Crystallography 2010-04-28 /pmc/articles/PMC2979110/ /pubmed/21579058 http://dx.doi.org/10.1107/S1600536810014753 Text en © Yang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Yang, Huai-Xia Zhang, Jun Ding, Ya-Nan Meng, Xiang-Ru catena-Poly[[(acetato-κ(2) O,O′)(methanol-κO)cadmium(II)]-μ-[1,2-bis(1H-benzimidazol-2-yl)ethane]-κ(2) N (3):N (3′)-[(acetato-κ(2) O,O′)(methanol-κO)cadmium(II)]-di-μ-chlorido] |
| title |
catena-Poly[[(acetato-κ(2)
O,O′)(methanol-κO)cadmium(II)]-μ-[1,2-bis(1H-benzimidazol-2-yl)ethane]-κ(2)
N
(3):N
(3′)-[(acetato-κ(2)
O,O′)(methanol-κO)cadmium(II)]-di-μ-chlorido] |
| title_full |
catena-Poly[[(acetato-κ(2)
O,O′)(methanol-κO)cadmium(II)]-μ-[1,2-bis(1H-benzimidazol-2-yl)ethane]-κ(2)
N
(3):N
(3′)-[(acetato-κ(2)
O,O′)(methanol-κO)cadmium(II)]-di-μ-chlorido] |
| title_fullStr |
catena-Poly[[(acetato-κ(2)
O,O′)(methanol-κO)cadmium(II)]-μ-[1,2-bis(1H-benzimidazol-2-yl)ethane]-κ(2)
N
(3):N
(3′)-[(acetato-κ(2)
O,O′)(methanol-κO)cadmium(II)]-di-μ-chlorido] |
| title_full_unstemmed |
catena-Poly[[(acetato-κ(2)
O,O′)(methanol-κO)cadmium(II)]-μ-[1,2-bis(1H-benzimidazol-2-yl)ethane]-κ(2)
N
(3):N
(3′)-[(acetato-κ(2)
O,O′)(methanol-κO)cadmium(II)]-di-μ-chlorido] |
| title_short |
catena-Poly[[(acetato-κ(2)
O,O′)(methanol-κO)cadmium(II)]-μ-[1,2-bis(1H-benzimidazol-2-yl)ethane]-κ(2)
N
(3):N
(3′)-[(acetato-κ(2)
O,O′)(methanol-κO)cadmium(II)]-di-μ-chlorido] |
| title_sort | catena-poly[[(acetato-κ(2)
o,o′)(methanol-κo)cadmium(ii)]-μ-[1,2-bis(1h-benzimidazol-2-yl)ethane]-κ(2)
n
(3):n
(3′)-[(acetato-κ(2)
o,o′)(methanol-κo)cadmium(ii)]-di-μ-chlorido] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979110/ https://www.ncbi.nlm.nih.gov/pubmed/21579058 http://dx.doi.org/10.1107/S1600536810014753 |
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