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Poly[tetrakis(2,2′-bipyridine)undeca-μ-oxido-hexaoxidodicopper(II)hexavanadium(V)]
In the title organic–inorganic hybrid vanadate complex, [Cu(2)V(6)O(17)(C(10)H(8)N(2))(4)](n), the Cu(II) atom is six-coordinated by two chelating 2,2′-bipyridine (bipy) ligands and two vanadate O atoms in a distorted octahedral geometry. Two [Cu(bipy)(2)V(3)O(8)] units are linked by a bridging O a...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979115/ https://www.ncbi.nlm.nih.gov/pubmed/21579049 http://dx.doi.org/10.1107/S1600536810014224 |
| _version_ | 1782191346915737600 |
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| author | Cui, Ji-Wen Cui, Xiao-Bing Yu, Hai-Hui Xu, Ji-Qing Wang, Shu-Hong |
| author_facet | Cui, Ji-Wen Cui, Xiao-Bing Yu, Hai-Hui Xu, Ji-Qing Wang, Shu-Hong |
| author_sort | Cui, Ji-Wen |
| collection | PubMed |
| description | In the title organic–inorganic hybrid vanadate complex, [Cu(2)V(6)O(17)(C(10)H(8)N(2))(4)](n), the Cu(II) atom is six-coordinated by two chelating 2,2′-bipyridine (bipy) ligands and two vanadate O atoms in a distorted octahedral geometry. Two [Cu(bipy)(2)V(3)O(8)] units are linked by a bridging O atom, which lies on an inversion center, forming a dimeric unit. The dimeric units are further connected by bridging vanadate O atoms into a two-dimensional layer parallel to (100). The layers are connected by weak C—H⋯O hydrogen bonds. |
| format | Text |
| id | pubmed-2979115 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29791152010-12-30 Poly[tetrakis(2,2′-bipyridine)undeca-μ-oxido-hexaoxidodicopper(II)hexavanadium(V)] Cui, Ji-Wen Cui, Xiao-Bing Yu, Hai-Hui Xu, Ji-Qing Wang, Shu-Hong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title organic–inorganic hybrid vanadate complex, [Cu(2)V(6)O(17)(C(10)H(8)N(2))(4)](n), the Cu(II) atom is six-coordinated by two chelating 2,2′-bipyridine (bipy) ligands and two vanadate O atoms in a distorted octahedral geometry. Two [Cu(bipy)(2)V(3)O(8)] units are linked by a bridging O atom, which lies on an inversion center, forming a dimeric unit. The dimeric units are further connected by bridging vanadate O atoms into a two-dimensional layer parallel to (100). The layers are connected by weak C—H⋯O hydrogen bonds. International Union of Crystallography 2010-04-24 /pmc/articles/PMC2979115/ /pubmed/21579049 http://dx.doi.org/10.1107/S1600536810014224 Text en © Cui et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Cui, Ji-Wen Cui, Xiao-Bing Yu, Hai-Hui Xu, Ji-Qing Wang, Shu-Hong Poly[tetrakis(2,2′-bipyridine)undeca-μ-oxido-hexaoxidodicopper(II)hexavanadium(V)] |
| title | Poly[tetrakis(2,2′-bipyridine)undeca-μ-oxido-hexaoxidodicopper(II)hexavanadium(V)] |
| title_full | Poly[tetrakis(2,2′-bipyridine)undeca-μ-oxido-hexaoxidodicopper(II)hexavanadium(V)] |
| title_fullStr | Poly[tetrakis(2,2′-bipyridine)undeca-μ-oxido-hexaoxidodicopper(II)hexavanadium(V)] |
| title_full_unstemmed | Poly[tetrakis(2,2′-bipyridine)undeca-μ-oxido-hexaoxidodicopper(II)hexavanadium(V)] |
| title_short | Poly[tetrakis(2,2′-bipyridine)undeca-μ-oxido-hexaoxidodicopper(II)hexavanadium(V)] |
| title_sort | poly[tetrakis(2,2′-bipyridine)undeca-μ-oxido-hexaoxidodicopper(ii)hexavanadium(v)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979115/ https://www.ncbi.nlm.nih.gov/pubmed/21579049 http://dx.doi.org/10.1107/S1600536810014224 |
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