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{μ-6,6′-Dimethoxy-2,2′-[butane-1,4-diylbis(nitrilomethylidyne)]diphenolato-1:2κ(8) O (6),O (1),O (1′),O (6′):O (1),N,N′,O (1′)}tris(nitrato-1κ(2) O,O′)copper(II)gadolinium(III)
In the title dinuclear complex, [CuGd(C(20)H(22)N(2)O(4))(NO(3))(3)], the Cu(II) ion is located in the inner N(2)O(2) cavity of the Schiff base ligand and adopts a distorted square-planar geometry. The Gd(III) ion is ten-coordinate being bound to ten O atoms, four from the Schiff base ligand and six...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979116/ https://www.ncbi.nlm.nih.gov/pubmed/21579057 http://dx.doi.org/10.1107/S1600536810014716 |
| _version_ | 1782191347142230016 |
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| author | Chan, Christopher Yang, Xiaoping Jones, Richard A. Holliday, Bradley J. Stanley, Julie M. |
| author_facet | Chan, Christopher Yang, Xiaoping Jones, Richard A. Holliday, Bradley J. Stanley, Julie M. |
| author_sort | Chan, Christopher |
| collection | PubMed |
| description | In the title dinuclear complex, [CuGd(C(20)H(22)N(2)O(4))(NO(3))(3)], the Cu(II) ion is located in the inner N(2)O(2) cavity of the Schiff base ligand and adopts a distorted square-planar geometry. The Gd(III) ion is ten-coordinate being bound to ten O atoms, four from the Schiff base ligand and six from three bidentate nitrate anions. The Cu(II) and Gd(III) ions are linked by two phenolate O atoms of the Schiff base ligand, with a separation of 3.5185 (9) Å. |
| format | Text |
| id | pubmed-2979116 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29791162010-12-30 {μ-6,6′-Dimethoxy-2,2′-[butane-1,4-diylbis(nitrilomethylidyne)]diphenolato-1:2κ(8) O (6),O (1),O (1′),O (6′):O (1),N,N′,O (1′)}tris(nitrato-1κ(2) O,O′)copper(II)gadolinium(III) Chan, Christopher Yang, Xiaoping Jones, Richard A. Holliday, Bradley J. Stanley, Julie M. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title dinuclear complex, [CuGd(C(20)H(22)N(2)O(4))(NO(3))(3)], the Cu(II) ion is located in the inner N(2)O(2) cavity of the Schiff base ligand and adopts a distorted square-planar geometry. The Gd(III) ion is ten-coordinate being bound to ten O atoms, four from the Schiff base ligand and six from three bidentate nitrate anions. The Cu(II) and Gd(III) ions are linked by two phenolate O atoms of the Schiff base ligand, with a separation of 3.5185 (9) Å. International Union of Crystallography 2010-04-28 /pmc/articles/PMC2979116/ /pubmed/21579057 http://dx.doi.org/10.1107/S1600536810014716 Text en © Chan et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Chan, Christopher Yang, Xiaoping Jones, Richard A. Holliday, Bradley J. Stanley, Julie M. {μ-6,6′-Dimethoxy-2,2′-[butane-1,4-diylbis(nitrilomethylidyne)]diphenolato-1:2κ(8) O (6),O (1),O (1′),O (6′):O (1),N,N′,O (1′)}tris(nitrato-1κ(2) O,O′)copper(II)gadolinium(III) |
| title | {μ-6,6′-Dimethoxy-2,2′-[butane-1,4-diylbis(nitrilomethylidyne)]diphenolato-1:2κ(8)
O
(6),O
(1),O
(1′),O
(6′):O
(1),N,N′,O
(1′)}tris(nitrato-1κ(2)
O,O′)copper(II)gadolinium(III) |
| title_full | {μ-6,6′-Dimethoxy-2,2′-[butane-1,4-diylbis(nitrilomethylidyne)]diphenolato-1:2κ(8)
O
(6),O
(1),O
(1′),O
(6′):O
(1),N,N′,O
(1′)}tris(nitrato-1κ(2)
O,O′)copper(II)gadolinium(III) |
| title_fullStr | {μ-6,6′-Dimethoxy-2,2′-[butane-1,4-diylbis(nitrilomethylidyne)]diphenolato-1:2κ(8)
O
(6),O
(1),O
(1′),O
(6′):O
(1),N,N′,O
(1′)}tris(nitrato-1κ(2)
O,O′)copper(II)gadolinium(III) |
| title_full_unstemmed | {μ-6,6′-Dimethoxy-2,2′-[butane-1,4-diylbis(nitrilomethylidyne)]diphenolato-1:2κ(8)
O
(6),O
(1),O
(1′),O
(6′):O
(1),N,N′,O
(1′)}tris(nitrato-1κ(2)
O,O′)copper(II)gadolinium(III) |
| title_short | {μ-6,6′-Dimethoxy-2,2′-[butane-1,4-diylbis(nitrilomethylidyne)]diphenolato-1:2κ(8)
O
(6),O
(1),O
(1′),O
(6′):O
(1),N,N′,O
(1′)}tris(nitrato-1κ(2)
O,O′)copper(II)gadolinium(III) |
| title_sort | {μ-6,6′-dimethoxy-2,2′-[butane-1,4-diylbis(nitrilomethylidyne)]diphenolato-1:2κ(8)
o
(6),o
(1),o
(1′),o
(6′):o
(1),n,n′,o
(1′)}tris(nitrato-1κ(2)
o,o′)copper(ii)gadolinium(iii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979116/ https://www.ncbi.nlm.nih.gov/pubmed/21579057 http://dx.doi.org/10.1107/S1600536810014716 |
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