6-Methyl­pyridine-2(1H)-thione

There are two unique mol­ecules in the asymmetric unit of the title pyridine­thione derivative, C(6)H(7)NS, each of which adopts the thione rather than the mercaptan form. The rings in both mol­ecules are essentially planar, with maximum deviations from the least-squares planes through all non-H ato...

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Autores principales: Lian, Guo-Jun, Chen, Bo, Zhang, Ting-Ting, Zhuang, Li-Zhen, Liang, Hong-Ze
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979122/
https://www.ncbi.nlm.nih.gov/pubmed/21579200
http://dx.doi.org/10.1107/S1600536810014273
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author Lian, Guo-Jun
Chen, Bo
Zhang, Ting-Ting
Zhuang, Li-Zhen
Liang, Hong-Ze
author_facet Lian, Guo-Jun
Chen, Bo
Zhang, Ting-Ting
Zhuang, Li-Zhen
Liang, Hong-Ze
author_sort Lian, Guo-Jun
collection PubMed
description There are two unique mol­ecules in the asymmetric unit of the title pyridine­thione derivative, C(6)H(7)NS, each of which adopts the thione rather than the mercaptan form. The rings in both mol­ecules are essentially planar, with maximum deviations from the least-squares planes through all non-H atoms of 0.021 (2) and 0.017 (2) Å. In the crystal structure, the mol­ecules form centrosymmetric cyclic dimers through inter­molecular N—H⋯S hydrogen bonds. Additional C—H(meth­yl)⋯S inter­actions generate a three-dimensional network.
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spelling pubmed-29791222010-12-30 6-Methyl­pyridine-2(1H)-thione Lian, Guo-Jun Chen, Bo Zhang, Ting-Ting Zhuang, Li-Zhen Liang, Hong-Ze Acta Crystallogr Sect E Struct Rep Online Organic Papers There are two unique mol­ecules in the asymmetric unit of the title pyridine­thione derivative, C(6)H(7)NS, each of which adopts the thione rather than the mercaptan form. The rings in both mol­ecules are essentially planar, with maximum deviations from the least-squares planes through all non-H atoms of 0.021 (2) and 0.017 (2) Å. In the crystal structure, the mol­ecules form centrosymmetric cyclic dimers through inter­molecular N—H⋯S hydrogen bonds. Additional C—H(meth­yl)⋯S inter­actions generate a three-dimensional network. International Union of Crystallography 2010-04-24 /pmc/articles/PMC2979122/ /pubmed/21579200 http://dx.doi.org/10.1107/S1600536810014273 Text en © Lian et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Lian, Guo-Jun
Chen, Bo
Zhang, Ting-Ting
Zhuang, Li-Zhen
Liang, Hong-Ze
6-Methyl­pyridine-2(1H)-thione
title 6-Methyl­pyridine-2(1H)-thione
title_full 6-Methyl­pyridine-2(1H)-thione
title_fullStr 6-Methyl­pyridine-2(1H)-thione
title_full_unstemmed 6-Methyl­pyridine-2(1H)-thione
title_short 6-Methyl­pyridine-2(1H)-thione
title_sort 6-methyl­pyridine-2(1h)-thione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979122/
https://www.ncbi.nlm.nih.gov/pubmed/21579200
http://dx.doi.org/10.1107/S1600536810014273
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AT zhuanglizhen 6methylpyridine21hthione
AT lianghongze 6methylpyridine21hthione

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