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Bis[bis(4,4′-dimethyl-2,2′-bipyridine)(10,11,12,13-tetrahydrodipyrido[3,2-a:2′,3′-c]phenazine)ruthenium(II)] tetrakis(perchlorate) acetonitrile disolvate monohydrate
The asymmetric unit of the title compound, [Ru(C(12)H(12)N(2))(2)(C(18)H(14)N(4))](2)(ClO(4))(4)·2CH(3)CN·H(2)O, contains two Ru(II) complex cations, four perchlorate counter-anions, two uncoordinated acetonitrile molecules and one water molecule. The Ru(II) ions are chelated by one 10,11,12,13-t...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979127/ https://www.ncbi.nlm.nih.gov/pubmed/21579038 http://dx.doi.org/10.1107/S1600536810014005 |
Sumario: | The asymmetric unit of the title compound, [Ru(C(12)H(12)N(2))(2)(C(18)H(14)N(4))](2)(ClO(4))(4)·2CH(3)CN·H(2)O, contains two Ru(II) complex cations, four perchlorate counter-anions, two uncoordinated acetonitrile molecules and one water molecule. The Ru(II) ions are chelated by one 10,11,12,13-tetrahydrodipyrido[3,2-a:2′,3′-c]phenazine (dpqc) and two 4,4′-dimethyl-2,2′-bipyridine (dmb) ligands in a distorted octahedral geometry. The uncoordinated water molecule is disordered over three positions, with occupancy factors of 0.398 (9), 0.312 (8) and 0.290 (8). A supramolecular structure is formed by weak π–π interactions between neighbouring molecules, with face-to-face distances of 3.51 (1) Å [centroid–centroid distance 3.81 (1) Å]. |
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