Bis[bis­(4,4′-dimethyl-2,2′-bipyridine)(10,11,12,13-tetra­hydro­dipyrido[3,2-a:2′,3′-c]phenazine)ruthenium(II)] tetra­kis(perchlorate) acetonitrile disolvate monohydrate

The asymmetric unit of the title compound, [Ru(C(12)H(12)N(2))(2)(C(18)H(14)N(4))](2)(ClO(4))(4)·2CH(3)CN·H(2)O, contains two Ru(II) complex cations, four perchlorate counter-anions, two uncoord­inated acetonitrile mol­ecules and one water mol­ecule. The Ru(II) ions are chelated by one 10,11,12,13-t...

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Detalles Bibliográficos
Autores principales: Zeng, ChengHui, Li, ZhengZheng, Liang, ZhenHua, Liu, YunJun, Wu, Fuhai
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979127/
https://www.ncbi.nlm.nih.gov/pubmed/21579038
http://dx.doi.org/10.1107/S1600536810014005
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author Zeng, ChengHui
Li, ZhengZheng
Liang, ZhenHua
Liu, YunJun
Wu, Fuhai
author_facet Zeng, ChengHui
Li, ZhengZheng
Liang, ZhenHua
Liu, YunJun
Wu, Fuhai
author_sort Zeng, ChengHui
collection PubMed
description The asymmetric unit of the title compound, [Ru(C(12)H(12)N(2))(2)(C(18)H(14)N(4))](2)(ClO(4))(4)·2CH(3)CN·H(2)O, contains two Ru(II) complex cations, four perchlorate counter-anions, two uncoord­inated acetonitrile mol­ecules and one water mol­ecule. The Ru(II) ions are chelated by one 10,11,12,13-tetra­hydro­dipyrido[3,2-a:2′,3′-c]phenazine (dpqc) and two 4,4′-dimethyl-2,2′-bipyridine (dmb) ligands in a distorted octa­hedral geometry. The uncoordinated water mol­ecule is disordered over three positions, with occupancy factors of 0.398 (9), 0.312 (8) and 0.290 (8). A supra­molecular structure is formed by weak π–π inter­actions between neighbouring mol­ecules, with face-to-face distances of 3.51 (1) Å [centroid–centroid distance 3.81 (1) Å].
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spelling pubmed-29791272010-12-30 Bis[bis­(4,4′-dimethyl-2,2′-bipyridine)(10,11,12,13-tetra­hydro­dipyrido[3,2-a:2′,3′-c]phenazine)ruthenium(II)] tetra­kis(perchlorate) acetonitrile disolvate monohydrate Zeng, ChengHui Li, ZhengZheng Liang, ZhenHua Liu, YunJun Wu, Fuhai Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Ru(C(12)H(12)N(2))(2)(C(18)H(14)N(4))](2)(ClO(4))(4)·2CH(3)CN·H(2)O, contains two Ru(II) complex cations, four perchlorate counter-anions, two uncoord­inated acetonitrile mol­ecules and one water mol­ecule. The Ru(II) ions are chelated by one 10,11,12,13-tetra­hydro­dipyrido[3,2-a:2′,3′-c]phenazine (dpqc) and two 4,4′-dimethyl-2,2′-bipyridine (dmb) ligands in a distorted octa­hedral geometry. The uncoordinated water mol­ecule is disordered over three positions, with occupancy factors of 0.398 (9), 0.312 (8) and 0.290 (8). A supra­molecular structure is formed by weak π–π inter­actions between neighbouring mol­ecules, with face-to-face distances of 3.51 (1) Å [centroid–centroid distance 3.81 (1) Å]. International Union of Crystallography 2010-04-21 /pmc/articles/PMC2979127/ /pubmed/21579038 http://dx.doi.org/10.1107/S1600536810014005 Text en © Zeng et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zeng, ChengHui
Li, ZhengZheng
Liang, ZhenHua
Liu, YunJun
Wu, Fuhai
Bis[bis­(4,4′-dimethyl-2,2′-bipyridine)(10,11,12,13-tetra­hydro­dipyrido[3,2-a:2′,3′-c]phenazine)ruthenium(II)] tetra­kis(perchlorate) acetonitrile disolvate monohydrate
title Bis[bis­(4,4′-dimethyl-2,2′-bipyridine)(10,11,12,13-tetra­hydro­dipyrido[3,2-a:2′,3′-c]phenazine)ruthenium(II)] tetra­kis(perchlorate) acetonitrile disolvate monohydrate
title_full Bis[bis­(4,4′-dimethyl-2,2′-bipyridine)(10,11,12,13-tetra­hydro­dipyrido[3,2-a:2′,3′-c]phenazine)ruthenium(II)] tetra­kis(perchlorate) acetonitrile disolvate monohydrate
title_fullStr Bis[bis­(4,4′-dimethyl-2,2′-bipyridine)(10,11,12,13-tetra­hydro­dipyrido[3,2-a:2′,3′-c]phenazine)ruthenium(II)] tetra­kis(perchlorate) acetonitrile disolvate monohydrate
title_full_unstemmed Bis[bis­(4,4′-dimethyl-2,2′-bipyridine)(10,11,12,13-tetra­hydro­dipyrido[3,2-a:2′,3′-c]phenazine)ruthenium(II)] tetra­kis(perchlorate) acetonitrile disolvate monohydrate
title_short Bis[bis­(4,4′-dimethyl-2,2′-bipyridine)(10,11,12,13-tetra­hydro­dipyrido[3,2-a:2′,3′-c]phenazine)ruthenium(II)] tetra­kis(perchlorate) acetonitrile disolvate monohydrate
title_sort bis[bis­(4,4′-dimethyl-2,2′-bipyridine)(10,11,12,13-tetra­hydro­dipyrido[3,2-a:2′,3′-c]phenazine)ruthenium(ii)] tetra­kis(perchlorate) acetonitrile disolvate monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979127/
https://www.ncbi.nlm.nih.gov/pubmed/21579038
http://dx.doi.org/10.1107/S1600536810014005
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AT liangzhenhua bisbis44dimethyl22bipyridine10111213tetrahydrodipyrido32a23cphenazinerutheniumiitetrakisperchlorateacetonitriledisolvatemonohydrate
AT liuyunjun bisbis44dimethyl22bipyridine10111213tetrahydrodipyrido32a23cphenazinerutheniumiitetrakisperchlorateacetonitriledisolvatemonohydrate
AT wufuhai bisbis44dimethyl22bipyridine10111213tetrahydrodipyrido32a23cphenazinerutheniumiitetrakisperchlorateacetonitriledisolvatemonohydrate

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