Cargando…

Diaqua­bis{5-carboxy-2-[(1H-1,2,4-triazol-1-yl)­meth­yl]-1H-imidazole-4-carboxyl­ato}­manganese(II)

In the title compound, [Mn(C(8)H(6)N(5)O(4))(2)(H(2)O)(2)], the Mn(II) ion is situated on an inversion center and is six-coordinated by two N and two O atoms from two L ligands (HL = 2-[(1H-1,2,4-triazol-1-yl)meth­yl]-1H-imidazole-4,5-dicarboxylic acid) and two water mol­ecules in a distorted octa­h...

Descripción completa

Detalles Bibliográficos
Autores principales: Ding, De-Gang, Tong, Yan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979128/
https://www.ncbi.nlm.nih.gov/pubmed/21579014
http://dx.doi.org/10.1107/S1600536810012626
_version_ 1782191349990162432
author Ding, De-Gang
Tong, Yan
author_facet Ding, De-Gang
Tong, Yan
author_sort Ding, De-Gang
collection PubMed
description In the title compound, [Mn(C(8)H(6)N(5)O(4))(2)(H(2)O)(2)], the Mn(II) ion is situated on an inversion center and is six-coordinated by two N and two O atoms from two L ligands (HL = 2-[(1H-1,2,4-triazol-1-yl)meth­yl]-1H-imidazole-4,5-dicarboxylic acid) and two water mol­ecules in a distorted octa­hedral geometry. In ligand L, the imidazole and triazole rings form a dihedral angle of 74.25 (8)°. Mol­ecules are assembled into a three-dimensional structure via inter­molecular O—H⋯O, O—H⋯N and N—H⋯N hydrogen-bonds, and π–π inter­actions with a short distance of 3.665 (2) Å between the centroids of the imidazole and triazole rings of neighbouring mol­ecules.
format Text
id pubmed-2979128
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29791282010-12-30 Diaqua­bis{5-carboxy-2-[(1H-1,2,4-triazol-1-yl)­meth­yl]-1H-imidazole-4-carboxyl­ato}­manganese(II) Ding, De-Gang Tong, Yan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mn(C(8)H(6)N(5)O(4))(2)(H(2)O)(2)], the Mn(II) ion is situated on an inversion center and is six-coordinated by two N and two O atoms from two L ligands (HL = 2-[(1H-1,2,4-triazol-1-yl)meth­yl]-1H-imidazole-4,5-dicarboxylic acid) and two water mol­ecules in a distorted octa­hedral geometry. In ligand L, the imidazole and triazole rings form a dihedral angle of 74.25 (8)°. Mol­ecules are assembled into a three-dimensional structure via inter­molecular O—H⋯O, O—H⋯N and N—H⋯N hydrogen-bonds, and π–π inter­actions with a short distance of 3.665 (2) Å between the centroids of the imidazole and triazole rings of neighbouring mol­ecules. International Union of Crystallography 2010-04-10 /pmc/articles/PMC2979128/ /pubmed/21579014 http://dx.doi.org/10.1107/S1600536810012626 Text en © Ding and Tong 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ding, De-Gang
Tong, Yan
Diaqua­bis{5-carboxy-2-[(1H-1,2,4-triazol-1-yl)­meth­yl]-1H-imidazole-4-carboxyl­ato}­manganese(II)
title Diaqua­bis{5-carboxy-2-[(1H-1,2,4-triazol-1-yl)­meth­yl]-1H-imidazole-4-carboxyl­ato}­manganese(II)
title_full Diaqua­bis{5-carboxy-2-[(1H-1,2,4-triazol-1-yl)­meth­yl]-1H-imidazole-4-carboxyl­ato}­manganese(II)
title_fullStr Diaqua­bis{5-carboxy-2-[(1H-1,2,4-triazol-1-yl)­meth­yl]-1H-imidazole-4-carboxyl­ato}­manganese(II)
title_full_unstemmed Diaqua­bis{5-carboxy-2-[(1H-1,2,4-triazol-1-yl)­meth­yl]-1H-imidazole-4-carboxyl­ato}­manganese(II)
title_short Diaqua­bis{5-carboxy-2-[(1H-1,2,4-triazol-1-yl)­meth­yl]-1H-imidazole-4-carboxyl­ato}­manganese(II)
title_sort diaqua­bis{5-carboxy-2-[(1h-1,2,4-triazol-1-yl)­meth­yl]-1h-imidazole-4-carboxyl­ato}­manganese(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979128/
https://www.ncbi.nlm.nih.gov/pubmed/21579014
http://dx.doi.org/10.1107/S1600536810012626
work_keys_str_mv AT dingdegang diaquabis5carboxy21h124triazol1ylmethyl1himidazole4carboxylatomanganeseii
AT tongyan diaquabis5carboxy21h124triazol1ylmethyl1himidazole4carboxylatomanganeseii