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Octa­kis(2-chloro­benz­yl)di-μ(2)-hydroxido-di-μ(3)-oxido-bis­(2-phenyl­acetato)tetra­tin(IV)

The asymmetric unit of the title compound, [Sn(4)(C(7)H(6)Cl)(8)(C(8)H(7)O(2))(2)O(2)(OH)(2)], comprises one-half of the centrosymmetric tin(IV) complex. μ(3)-Oxide and μ(2)-hydroxide bridges link the four five-coordinate Sn(IV) atoms to generate three fused four-membered Sn—O—Sn—O rings in a ladder...

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Detalles Bibliográficos
Autores principales: Peng, Wei-Bing, Li, Guo-Qiang, Yin, Handong, Zhao, Xianhe
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979133/
https://www.ncbi.nlm.nih.gov/pubmed/21579028
http://dx.doi.org/10.1107/S1600536810012559
Descripción
Sumario:The asymmetric unit of the title compound, [Sn(4)(C(7)H(6)Cl)(8)(C(8)H(7)O(2))(2)O(2)(OH)(2)], comprises one-half of the centrosymmetric tin(IV) complex. μ(3)-Oxide and μ(2)-hydroxide bridges link the four five-coordinate Sn(IV) atoms to generate three fused four-membered Sn—O—Sn—O rings in a ladder-like structure. The two endocyclic Sn atoms each bind to two μ(3)-oxide anions and a μ(2)-hydroxide ligand, together with two 2-chloro­benzyl groups. The exocyclic Sn atoms each carry a monodentate phenyl­acetate ligand, two 2-chloro­benzyl groups, and μ(3)-oxide and μ(2)-hydroxide ligands. Both types of Sn atoms adopt a distorted trigonal–bipyramidal coordination geometry. The mol­ecular conformation is stabilized by intra­molecular O—H⋯O inter­actions involving the μ(2)-hydroxide ligands and the C=O group of the phenyl­acetate ligand.