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Octa­kis(2-chloro­benz­yl)di-μ(2)-hydroxido-di-μ(3)-oxido-bis­(2-phenyl­acetato)tetra­tin(IV)

The asymmetric unit of the title compound, [Sn(4)(C(7)H(6)Cl)(8)(C(8)H(7)O(2))(2)O(2)(OH)(2)], comprises one-half of the centrosymmetric tin(IV) complex. μ(3)-Oxide and μ(2)-hydroxide bridges link the four five-coordinate Sn(IV) atoms to generate three fused four-membered Sn—O—Sn—O rings in a ladder...

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Detalles Bibliográficos
Autores principales: Peng, Wei-Bing, Li, Guo-Qiang, Yin, Handong, Zhao, Xianhe
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979133/
https://www.ncbi.nlm.nih.gov/pubmed/21579028
http://dx.doi.org/10.1107/S1600536810012559
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author Peng, Wei-Bing
Li, Guo-Qiang
Yin, Handong
Zhao, Xianhe
author_facet Peng, Wei-Bing
Li, Guo-Qiang
Yin, Handong
Zhao, Xianhe
author_sort Peng, Wei-Bing
collection PubMed
description The asymmetric unit of the title compound, [Sn(4)(C(7)H(6)Cl)(8)(C(8)H(7)O(2))(2)O(2)(OH)(2)], comprises one-half of the centrosymmetric tin(IV) complex. μ(3)-Oxide and μ(2)-hydroxide bridges link the four five-coordinate Sn(IV) atoms to generate three fused four-membered Sn—O—Sn—O rings in a ladder-like structure. The two endocyclic Sn atoms each bind to two μ(3)-oxide anions and a μ(2)-hydroxide ligand, together with two 2-chloro­benzyl groups. The exocyclic Sn atoms each carry a monodentate phenyl­acetate ligand, two 2-chloro­benzyl groups, and μ(3)-oxide and μ(2)-hydroxide ligands. Both types of Sn atoms adopt a distorted trigonal–bipyramidal coordination geometry. The mol­ecular conformation is stabilized by intra­molecular O—H⋯O inter­actions involving the μ(2)-hydroxide ligands and the C=O group of the phenyl­acetate ligand.
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spelling pubmed-29791332010-12-30 Octa­kis(2-chloro­benz­yl)di-μ(2)-hydroxido-di-μ(3)-oxido-bis­(2-phenyl­acetato)tetra­tin(IV) Peng, Wei-Bing Li, Guo-Qiang Yin, Handong Zhao, Xianhe Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Sn(4)(C(7)H(6)Cl)(8)(C(8)H(7)O(2))(2)O(2)(OH)(2)], comprises one-half of the centrosymmetric tin(IV) complex. μ(3)-Oxide and μ(2)-hydroxide bridges link the four five-coordinate Sn(IV) atoms to generate three fused four-membered Sn—O—Sn—O rings in a ladder-like structure. The two endocyclic Sn atoms each bind to two μ(3)-oxide anions and a μ(2)-hydroxide ligand, together with two 2-chloro­benzyl groups. The exocyclic Sn atoms each carry a monodentate phenyl­acetate ligand, two 2-chloro­benzyl groups, and μ(3)-oxide and μ(2)-hydroxide ligands. Both types of Sn atoms adopt a distorted trigonal–bipyramidal coordination geometry. The mol­ecular conformation is stabilized by intra­molecular O—H⋯O inter­actions involving the μ(2)-hydroxide ligands and the C=O group of the phenyl­acetate ligand. International Union of Crystallography 2010-04-17 /pmc/articles/PMC2979133/ /pubmed/21579028 http://dx.doi.org/10.1107/S1600536810012559 Text en © Peng et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Peng, Wei-Bing
Li, Guo-Qiang
Yin, Handong
Zhao, Xianhe
Octa­kis(2-chloro­benz­yl)di-μ(2)-hydroxido-di-μ(3)-oxido-bis­(2-phenyl­acetato)tetra­tin(IV)
title Octa­kis(2-chloro­benz­yl)di-μ(2)-hydroxido-di-μ(3)-oxido-bis­(2-phenyl­acetato)tetra­tin(IV)
title_full Octa­kis(2-chloro­benz­yl)di-μ(2)-hydroxido-di-μ(3)-oxido-bis­(2-phenyl­acetato)tetra­tin(IV)
title_fullStr Octa­kis(2-chloro­benz­yl)di-μ(2)-hydroxido-di-μ(3)-oxido-bis­(2-phenyl­acetato)tetra­tin(IV)
title_full_unstemmed Octa­kis(2-chloro­benz­yl)di-μ(2)-hydroxido-di-μ(3)-oxido-bis­(2-phenyl­acetato)tetra­tin(IV)
title_short Octa­kis(2-chloro­benz­yl)di-μ(2)-hydroxido-di-μ(3)-oxido-bis­(2-phenyl­acetato)tetra­tin(IV)
title_sort octa­kis(2-chloro­benz­yl)di-μ(2)-hydroxido-di-μ(3)-oxido-bis­(2-phenyl­acetato)tetra­tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979133/
https://www.ncbi.nlm.nih.gov/pubmed/21579028
http://dx.doi.org/10.1107/S1600536810012559
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