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Octakis(2-chlorobenzyl)di-μ(2)-hydroxido-di-μ(3)-oxido-bis(2-phenylacetato)tetratin(IV)
The asymmetric unit of the title compound, [Sn(4)(C(7)H(6)Cl)(8)(C(8)H(7)O(2))(2)O(2)(OH)(2)], comprises one-half of the centrosymmetric tin(IV) complex. μ(3)-Oxide and μ(2)-hydroxide bridges link the four five-coordinate Sn(IV) atoms to generate three fused four-membered Sn—O—Sn—O rings in a ladder...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979133/ https://www.ncbi.nlm.nih.gov/pubmed/21579028 http://dx.doi.org/10.1107/S1600536810012559 |
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author | Peng, Wei-Bing Li, Guo-Qiang Yin, Handong Zhao, Xianhe |
author_facet | Peng, Wei-Bing Li, Guo-Qiang Yin, Handong Zhao, Xianhe |
author_sort | Peng, Wei-Bing |
collection | PubMed |
description | The asymmetric unit of the title compound, [Sn(4)(C(7)H(6)Cl)(8)(C(8)H(7)O(2))(2)O(2)(OH)(2)], comprises one-half of the centrosymmetric tin(IV) complex. μ(3)-Oxide and μ(2)-hydroxide bridges link the four five-coordinate Sn(IV) atoms to generate three fused four-membered Sn—O—Sn—O rings in a ladder-like structure. The two endocyclic Sn atoms each bind to two μ(3)-oxide anions and a μ(2)-hydroxide ligand, together with two 2-chlorobenzyl groups. The exocyclic Sn atoms each carry a monodentate phenylacetate ligand, two 2-chlorobenzyl groups, and μ(3)-oxide and μ(2)-hydroxide ligands. Both types of Sn atoms adopt a distorted trigonal–bipyramidal coordination geometry. The molecular conformation is stabilized by intramolecular O—H⋯O interactions involving the μ(2)-hydroxide ligands and the C=O group of the phenylacetate ligand. |
format | Text |
id | pubmed-2979133 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29791332010-12-30 Octakis(2-chlorobenzyl)di-μ(2)-hydroxido-di-μ(3)-oxido-bis(2-phenylacetato)tetratin(IV) Peng, Wei-Bing Li, Guo-Qiang Yin, Handong Zhao, Xianhe Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Sn(4)(C(7)H(6)Cl)(8)(C(8)H(7)O(2))(2)O(2)(OH)(2)], comprises one-half of the centrosymmetric tin(IV) complex. μ(3)-Oxide and μ(2)-hydroxide bridges link the four five-coordinate Sn(IV) atoms to generate three fused four-membered Sn—O—Sn—O rings in a ladder-like structure. The two endocyclic Sn atoms each bind to two μ(3)-oxide anions and a μ(2)-hydroxide ligand, together with two 2-chlorobenzyl groups. The exocyclic Sn atoms each carry a monodentate phenylacetate ligand, two 2-chlorobenzyl groups, and μ(3)-oxide and μ(2)-hydroxide ligands. Both types of Sn atoms adopt a distorted trigonal–bipyramidal coordination geometry. The molecular conformation is stabilized by intramolecular O—H⋯O interactions involving the μ(2)-hydroxide ligands and the C=O group of the phenylacetate ligand. International Union of Crystallography 2010-04-17 /pmc/articles/PMC2979133/ /pubmed/21579028 http://dx.doi.org/10.1107/S1600536810012559 Text en © Peng et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Peng, Wei-Bing Li, Guo-Qiang Yin, Handong Zhao, Xianhe Octakis(2-chlorobenzyl)di-μ(2)-hydroxido-di-μ(3)-oxido-bis(2-phenylacetato)tetratin(IV) |
title | Octakis(2-chlorobenzyl)di-μ(2)-hydroxido-di-μ(3)-oxido-bis(2-phenylacetato)tetratin(IV) |
title_full | Octakis(2-chlorobenzyl)di-μ(2)-hydroxido-di-μ(3)-oxido-bis(2-phenylacetato)tetratin(IV) |
title_fullStr | Octakis(2-chlorobenzyl)di-μ(2)-hydroxido-di-μ(3)-oxido-bis(2-phenylacetato)tetratin(IV) |
title_full_unstemmed | Octakis(2-chlorobenzyl)di-μ(2)-hydroxido-di-μ(3)-oxido-bis(2-phenylacetato)tetratin(IV) |
title_short | Octakis(2-chlorobenzyl)di-μ(2)-hydroxido-di-μ(3)-oxido-bis(2-phenylacetato)tetratin(IV) |
title_sort | octakis(2-chlorobenzyl)di-μ(2)-hydroxido-di-μ(3)-oxido-bis(2-phenylacetato)tetratin(iv) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979133/ https://www.ncbi.nlm.nih.gov/pubmed/21579028 http://dx.doi.org/10.1107/S1600536810012559 |
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