1-[(E)-(2-Phenoxy­anilino)methyl­ene]naphthalen-2(1H)-one

The mol­ecule of the title compound, C(23)H(17)NO(2), a Schiff base derived from 2-hydr­oxy-1-naphthaldehyde, crystallizes in the keto–amine tautomeric form. The dihedral angle between the aniline and hydroxy­benzene rings is 77.41 (17)°, whereas the planes of the naphthaldehyde and fused aniline be...

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Detalles Bibliográficos
Autores principales: Temel, Ersin, Ağar, Erbil, Büyükgüngör, Orhan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979135/
https://www.ncbi.nlm.nih.gov/pubmed/21579180
http://dx.doi.org/10.1107/S1600536810013851
Descripción
Sumario:The mol­ecule of the title compound, C(23)H(17)NO(2), a Schiff base derived from 2-hydr­oxy-1-naphthaldehyde, crystallizes in the keto–amine tautomeric form. The dihedral angle between the aniline and hydroxy­benzene rings is 77.41 (17)°, whereas the planes of the naphthaldehyde and fused aniline benzene rings are nearly coplanar, making a dihedral angle of 8.29 (15)°. Intra­molecular N—H⋯O hydrogen bonding, a characteristic hydrogen bond for Schiff bases, helps to stabilize the mol­ecular structure. Weak inter­molecular C—H⋯π inter­actions are present in the crystal structure.

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