n-Butyl­dichlorido{4-cyclo­hexyl-1-[phenyl(2-pyridyl-κN)methyl­ene]­thiosemicarbazidato-κ(2) N (1),S}tin(IV) chloro­form monosolvate

The monodeprotonated Schiff base ligand in the title com­pound, [Sn(C(4)H(9))(C(19)H(21)N(4)S)Cl(2)]·CHCl(3), N,N′,S-chelates to the Sn atom, which is six-coordinated in an octa­hedral environment. The three coordinating atoms along with the butyl C atom comprise a square plane, above and below whic...

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Detalles Bibliográficos
Autores principales: Affan, Md. Abu, Salam, Md. Abdus, Farina, Yang, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979137/
https://www.ncbi.nlm.nih.gov/pubmed/21579052
http://dx.doi.org/10.1107/S1600536810014455
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author Affan, Md. Abu
Salam, Md. Abdus
Farina, Yang
Ng, Seik Weng
author_facet Affan, Md. Abu
Salam, Md. Abdus
Farina, Yang
Ng, Seik Weng
author_sort Affan, Md. Abu
collection PubMed
description The monodeprotonated Schiff base ligand in the title com­pound, [Sn(C(4)H(9))(C(19)H(21)N(4)S)Cl(2)]·CHCl(3), N,N′,S-chelates to the Sn atom, which is six-coordinated in an octa­hedral environment. The three coordinating atoms along with the butyl C atom comprise a square plane, above and below which are positioned the Cl atoms. The amino group is a hydrogen-bond donor to a Cl atom of an adjacent mol­ecule, the hydrogen bond giving rise to a helical chain propagating in [010]. The Cl and H atoms of the chloro­form mol­ecule are disordered over two positions in an 0.67:0.33 ratio.
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spelling pubmed-29791372010-12-30 n-Butyl­dichlorido{4-cyclo­hexyl-1-[phenyl(2-pyridyl-κN)methyl­ene]­thiosemicarbazidato-κ(2) N (1),S}tin(IV) chloro­form monosolvate Affan, Md. Abu Salam, Md. Abdus Farina, Yang Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The monodeprotonated Schiff base ligand in the title com­pound, [Sn(C(4)H(9))(C(19)H(21)N(4)S)Cl(2)]·CHCl(3), N,N′,S-chelates to the Sn atom, which is six-coordinated in an octa­hedral environment. The three coordinating atoms along with the butyl C atom comprise a square plane, above and below which are positioned the Cl atoms. The amino group is a hydrogen-bond donor to a Cl atom of an adjacent mol­ecule, the hydrogen bond giving rise to a helical chain propagating in [010]. The Cl and H atoms of the chloro­form mol­ecule are disordered over two positions in an 0.67:0.33 ratio. International Union of Crystallography 2010-04-24 /pmc/articles/PMC2979137/ /pubmed/21579052 http://dx.doi.org/10.1107/S1600536810014455 Text en © Affan et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Affan, Md. Abu
Salam, Md. Abdus
Farina, Yang
Ng, Seik Weng
n-Butyl­dichlorido{4-cyclo­hexyl-1-[phenyl(2-pyridyl-κN)methyl­ene]­thiosemicarbazidato-κ(2) N (1),S}tin(IV) chloro­form monosolvate
title n-Butyl­dichlorido{4-cyclo­hexyl-1-[phenyl(2-pyridyl-κN)methyl­ene]­thiosemicarbazidato-κ(2) N (1),S}tin(IV) chloro­form monosolvate
title_full n-Butyl­dichlorido{4-cyclo­hexyl-1-[phenyl(2-pyridyl-κN)methyl­ene]­thiosemicarbazidato-κ(2) N (1),S}tin(IV) chloro­form monosolvate
title_fullStr n-Butyl­dichlorido{4-cyclo­hexyl-1-[phenyl(2-pyridyl-κN)methyl­ene]­thiosemicarbazidato-κ(2) N (1),S}tin(IV) chloro­form monosolvate
title_full_unstemmed n-Butyl­dichlorido{4-cyclo­hexyl-1-[phenyl(2-pyridyl-κN)methyl­ene]­thiosemicarbazidato-κ(2) N (1),S}tin(IV) chloro­form monosolvate
title_short n-Butyl­dichlorido{4-cyclo­hexyl-1-[phenyl(2-pyridyl-κN)methyl­ene]­thiosemicarbazidato-κ(2) N (1),S}tin(IV) chloro­form monosolvate
title_sort n-butyl­dichlorido{4-cyclo­hexyl-1-[phenyl(2-pyridyl-κn)methyl­ene]­thiosemicarbazidato-κ(2) n (1),s}tin(iv) chloro­form monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979137/
https://www.ncbi.nlm.nih.gov/pubmed/21579052
http://dx.doi.org/10.1107/S1600536810014455
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