Biphenyl-4-yl 2,2,2-trichloro­ethyl sulfate

The mol­ecular structure of the title compound, C(14)H(11)Cl(3)O(4)S, displays a biphenyl dihedral angle of 4.9 (2)° between the benzene rings, which is significantly smaller than the calculated dihedral angle of 41.2° of biphenyl derivatives without ortho substituents. The C(Ar)—O bond length of 1....

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Detalles Bibliográficos
Autores principales: Li, Xueshu, Parkin, Sean, Duffel, Michael W., Robertson, Larry W., Lehmler, Hans-Joachim
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979148/
https://www.ncbi.nlm.nih.gov/pubmed/21579128
http://dx.doi.org/10.1107/S1600536810012845
Descripción
Sumario:The mol­ecular structure of the title compound, C(14)H(11)Cl(3)O(4)S, displays a biphenyl dihedral angle of 4.9 (2)° between the benzene rings, which is significantly smaller than the calculated dihedral angle of 41.2° of biphenyl derivatives without ortho substituents. The C(Ar)—O bond length of 1.432 (4) Å is comparable with other sulfuric acid biphenyl-4-yl ester 2,2,2-trichloro­ether ester derivatives without electronegative substituents in the sulfated phenyl ring.

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