Biphenyl-4-yl 2,2,2-trichloro­ethyl sulfate

The mol­ecular structure of the title compound, C(14)H(11)Cl(3)O(4)S, displays a biphenyl dihedral angle of 4.9 (2)° between the benzene rings, which is significantly smaller than the calculated dihedral angle of 41.2° of biphenyl derivatives without ortho substituents. The C(Ar)—O bond length of 1....

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Detalles Bibliográficos
Autores principales: Li, Xueshu, Parkin, Sean, Duffel, Michael W., Robertson, Larry W., Lehmler, Hans-Joachim
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979148/
https://www.ncbi.nlm.nih.gov/pubmed/21579128
http://dx.doi.org/10.1107/S1600536810012845
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author Li, Xueshu
Parkin, Sean
Duffel, Michael W.
Robertson, Larry W.
Lehmler, Hans-Joachim
author_facet Li, Xueshu
Parkin, Sean
Duffel, Michael W.
Robertson, Larry W.
Lehmler, Hans-Joachim
author_sort Li, Xueshu
collection PubMed
description The mol­ecular structure of the title compound, C(14)H(11)Cl(3)O(4)S, displays a biphenyl dihedral angle of 4.9 (2)° between the benzene rings, which is significantly smaller than the calculated dihedral angle of 41.2° of biphenyl derivatives without ortho substituents. The C(Ar)—O bond length of 1.432 (4) Å is comparable with other sulfuric acid biphenyl-4-yl ester 2,2,2-trichloro­ether ester derivatives without electronegative substituents in the sulfated phenyl ring.
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spelling pubmed-29791482010-12-30 Biphenyl-4-yl 2,2,2-trichloro­ethyl sulfate Li, Xueshu Parkin, Sean Duffel, Michael W. Robertson, Larry W. Lehmler, Hans-Joachim Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecular structure of the title compound, C(14)H(11)Cl(3)O(4)S, displays a biphenyl dihedral angle of 4.9 (2)° between the benzene rings, which is significantly smaller than the calculated dihedral angle of 41.2° of biphenyl derivatives without ortho substituents. The C(Ar)—O bond length of 1.432 (4) Å is comparable with other sulfuric acid biphenyl-4-yl ester 2,2,2-trichloro­ether ester derivatives without electronegative substituents in the sulfated phenyl ring. International Union of Crystallography 2010-04-14 /pmc/articles/PMC2979148/ /pubmed/21579128 http://dx.doi.org/10.1107/S1600536810012845 Text en © Li et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, Xueshu
Parkin, Sean
Duffel, Michael W.
Robertson, Larry W.
Lehmler, Hans-Joachim
Biphenyl-4-yl 2,2,2-trichloro­ethyl sulfate
title Biphenyl-4-yl 2,2,2-trichloro­ethyl sulfate
title_full Biphenyl-4-yl 2,2,2-trichloro­ethyl sulfate
title_fullStr Biphenyl-4-yl 2,2,2-trichloro­ethyl sulfate
title_full_unstemmed Biphenyl-4-yl 2,2,2-trichloro­ethyl sulfate
title_short Biphenyl-4-yl 2,2,2-trichloro­ethyl sulfate
title_sort biphenyl-4-yl 2,2,2-trichloro­ethyl sulfate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979148/
https://www.ncbi.nlm.nih.gov/pubmed/21579128
http://dx.doi.org/10.1107/S1600536810012845
work_keys_str_mv AT lixueshu biphenyl4yl222trichloroethylsulfate
AT parkinsean biphenyl4yl222trichloroethylsulfate
AT duffelmichaelw biphenyl4yl222trichloroethylsulfate
AT robertsonlarryw biphenyl4yl222trichloroethylsulfate
AT lehmlerhansjoachim biphenyl4yl222trichloroethylsulfate

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