Tetra­kis(8-quinolinolato-κ(2) N,O)hafnium(IV) dimethyl­formamide solvate monohydrate

In the title compound, [Hf(C(9)H(6)NO)]·C(3)H(7)NO·H(2)O, the hafnium(IV) atom is coordinated by four 8-quinolinolate (Ox) ligands, forming a slightly distorted square-anti­prismatic coordination polyhedron. The crystal packing is controlled by O—H⋯O and C—H⋯O hydrogen-bonding inter­actions and π–π...

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Detalles Bibliográficos
Autores principales: Viljoen, Johannes A., Visser, Hendrik G., Roodt, Andreas
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979151/
https://www.ncbi.nlm.nih.gov/pubmed/21579072
http://dx.doi.org/10.1107/S1600536810014960
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author Viljoen, Johannes A.
Visser, Hendrik G.
Roodt, Andreas
author_facet Viljoen, Johannes A.
Visser, Hendrik G.
Roodt, Andreas
author_sort Viljoen, Johannes A.
collection PubMed
description In the title compound, [Hf(C(9)H(6)NO)]·C(3)H(7)NO·H(2)O, the hafnium(IV) atom is coordinated by four 8-quinolinolate (Ox) ligands, forming a slightly distorted square-anti­prismatic coordination polyhedron. The crystal packing is controlled by O—H⋯O and C—H⋯O hydrogen-bonding inter­actions and π–π inter­actions between quinoline ligands of neighbouring mol­ecules. The inter­planar distances vary between 3.150 (1) and 3.251 (2) Å, while centroid–centroid distances vary from 3.589 (1) to 4.1531 (1) Å.
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spelling pubmed-29791512010-12-30 Tetra­kis(8-quinolinolato-κ(2) N,O)hafnium(IV) dimethyl­formamide solvate monohydrate Viljoen, Johannes A. Visser, Hendrik G. Roodt, Andreas Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Hf(C(9)H(6)NO)]·C(3)H(7)NO·H(2)O, the hafnium(IV) atom is coordinated by four 8-quinolinolate (Ox) ligands, forming a slightly distorted square-anti­prismatic coordination polyhedron. The crystal packing is controlled by O—H⋯O and C—H⋯O hydrogen-bonding inter­actions and π–π inter­actions between quinoline ligands of neighbouring mol­ecules. The inter­planar distances vary between 3.150 (1) and 3.251 (2) Å, while centroid–centroid distances vary from 3.589 (1) to 4.1531 (1) Å. International Union of Crystallography 2010-04-30 /pmc/articles/PMC2979151/ /pubmed/21579072 http://dx.doi.org/10.1107/S1600536810014960 Text en © Viljoen et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Viljoen, Johannes A.
Visser, Hendrik G.
Roodt, Andreas
Tetra­kis(8-quinolinolato-κ(2) N,O)hafnium(IV) dimethyl­formamide solvate monohydrate
title Tetra­kis(8-quinolinolato-κ(2) N,O)hafnium(IV) dimethyl­formamide solvate monohydrate
title_full Tetra­kis(8-quinolinolato-κ(2) N,O)hafnium(IV) dimethyl­formamide solvate monohydrate
title_fullStr Tetra­kis(8-quinolinolato-κ(2) N,O)hafnium(IV) dimethyl­formamide solvate monohydrate
title_full_unstemmed Tetra­kis(8-quinolinolato-κ(2) N,O)hafnium(IV) dimethyl­formamide solvate monohydrate
title_short Tetra­kis(8-quinolinolato-κ(2) N,O)hafnium(IV) dimethyl­formamide solvate monohydrate
title_sort tetra­kis(8-quinolinolato-κ(2) n,o)hafnium(iv) dimethyl­formamide solvate monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979151/
https://www.ncbi.nlm.nih.gov/pubmed/21579072
http://dx.doi.org/10.1107/S1600536810014960
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