Tetra­aqua­bis(1,10-phenanthroline)bis­[μ(2)-1H-pyrazole-3,5-dicarboxyl­ato(3−)]tricopper(II) dihydrate

The title compound, [Cu(3)(C(5)HN(2)O(4))(2)(C(12)H(8)N(2))(2)(H(2)O)(4)]·2H(2)O, is a trinuclear copper(II) complex in which two centrosymmetrically related pyrazole-3,5-dicarboxyl­ate(3−) and 1,10-phenanthroline ligands bind three Cu(II) atoms, with one Cu(II) atom located on a center of symmetry....

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Autores principales: Li, Zhi-Gang, Li, Shao-Ai, Liu, De-Quan, He, Long, Xu, Jing-Wei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979153/
https://www.ncbi.nlm.nih.gov/pubmed/21579043
http://dx.doi.org/10.1107/S1600536810012833
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author Li, Zhi-Gang
Li, Shao-Ai
Liu, De-Quan
He, Long
Xu, Jing-Wei
author_facet Li, Zhi-Gang
Li, Shao-Ai
Liu, De-Quan
He, Long
Xu, Jing-Wei
author_sort Li, Zhi-Gang
collection PubMed
description The title compound, [Cu(3)(C(5)HN(2)O(4))(2)(C(12)H(8)N(2))(2)(H(2)O)(4)]·2H(2)O, is a trinuclear copper(II) complex in which two centrosymmetrically related pyrazole-3,5-dicarboxyl­ate(3−) and 1,10-phenanthroline ligands bind three Cu(II) atoms, with one Cu(II) atom located on a center of symmetry. In each complex, there are four coordinated water mol­ecules and two solvent water mol­ecules, which participate in extensive hydrogen-bond patterns. These inter­actions, as well as π–π inter­actions between neighbouring 1,10-phenanthroline ligands [shortest atom-to-atom distance = 3.363 (3) Å], extend the crystal structure into a three-dimensional supra­molecular network.
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spelling pubmed-29791532010-12-30 Tetra­aqua­bis(1,10-phenanthroline)bis­[μ(2)-1H-pyrazole-3,5-dicarboxyl­ato(3−)]tricopper(II) dihydrate Li, Zhi-Gang Li, Shao-Ai Liu, De-Quan He, Long Xu, Jing-Wei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(3)(C(5)HN(2)O(4))(2)(C(12)H(8)N(2))(2)(H(2)O)(4)]·2H(2)O, is a trinuclear copper(II) complex in which two centrosymmetrically related pyrazole-3,5-dicarboxyl­ate(3−) and 1,10-phenanthroline ligands bind three Cu(II) atoms, with one Cu(II) atom located on a center of symmetry. In each complex, there are four coordinated water mol­ecules and two solvent water mol­ecules, which participate in extensive hydrogen-bond patterns. These inter­actions, as well as π–π inter­actions between neighbouring 1,10-phenanthroline ligands [shortest atom-to-atom distance = 3.363 (3) Å], extend the crystal structure into a three-dimensional supra­molecular network. International Union of Crystallography 2010-04-24 /pmc/articles/PMC2979153/ /pubmed/21579043 http://dx.doi.org/10.1107/S1600536810012833 Text en © Li et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Zhi-Gang
Li, Shao-Ai
Liu, De-Quan
He, Long
Xu, Jing-Wei
Tetra­aqua­bis(1,10-phenanthroline)bis­[μ(2)-1H-pyrazole-3,5-dicarboxyl­ato(3−)]tricopper(II) dihydrate
title Tetra­aqua­bis(1,10-phenanthroline)bis­[μ(2)-1H-pyrazole-3,5-dicarboxyl­ato(3−)]tricopper(II) dihydrate
title_full Tetra­aqua­bis(1,10-phenanthroline)bis­[μ(2)-1H-pyrazole-3,5-dicarboxyl­ato(3−)]tricopper(II) dihydrate
title_fullStr Tetra­aqua­bis(1,10-phenanthroline)bis­[μ(2)-1H-pyrazole-3,5-dicarboxyl­ato(3−)]tricopper(II) dihydrate
title_full_unstemmed Tetra­aqua­bis(1,10-phenanthroline)bis­[μ(2)-1H-pyrazole-3,5-dicarboxyl­ato(3−)]tricopper(II) dihydrate
title_short Tetra­aqua­bis(1,10-phenanthroline)bis­[μ(2)-1H-pyrazole-3,5-dicarboxyl­ato(3−)]tricopper(II) dihydrate
title_sort tetra­aqua­bis(1,10-phenanthroline)bis­[μ(2)-1h-pyrazole-3,5-dicarboxyl­ato(3−)]tricopper(ii) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979153/
https://www.ncbi.nlm.nih.gov/pubmed/21579043
http://dx.doi.org/10.1107/S1600536810012833
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