Ethyl 1-tert-butyl-2-(4-hydr­oxy-3-methoxy­phen­yl)-1H-benzimidazole-5-carboxyl­ate

In the title compound, C(21)H(24)N(2)O(4), the benzimidazole ring system is almost planar, with a maximum deviation of 0.047 (1) Å and makes a dihedral angle of 88.44 (5)° with the attached benzene ring. In the crystal, mol­ecules form infinite chains along the b axis by way of inter­molecular O—H⋯N...

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Detalles Bibliográficos
Autores principales: Arumugam, Natarajan, Abdul Rahim, Aisyah Saad, Osman, Hasnah, Rosli, Mohd Mustaqim, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979157/
https://www.ncbi.nlm.nih.gov/pubmed/21579111
http://dx.doi.org/10.1107/S1600536810011918
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author Arumugam, Natarajan
Abdul Rahim, Aisyah Saad
Osman, Hasnah
Rosli, Mohd Mustaqim
Fun, Hoong-Kun
author_facet Arumugam, Natarajan
Abdul Rahim, Aisyah Saad
Osman, Hasnah
Rosli, Mohd Mustaqim
Fun, Hoong-Kun
author_sort Arumugam, Natarajan
collection PubMed
description In the title compound, C(21)H(24)N(2)O(4), the benzimidazole ring system is almost planar, with a maximum deviation of 0.047 (1) Å and makes a dihedral angle of 88.44 (5)° with the attached benzene ring. In the crystal, mol­ecules form infinite chains along the b axis by way of inter­molecular O—H⋯N and C—H⋯O inter­actions. Weak C—H⋯π also contribute to the stabilization of the crystal structure.
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spelling pubmed-29791572010-12-30 Ethyl 1-tert-butyl-2-(4-hydr­oxy-3-methoxy­phen­yl)-1H-benzimidazole-5-carboxyl­ate Arumugam, Natarajan Abdul Rahim, Aisyah Saad Osman, Hasnah Rosli, Mohd Mustaqim Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(21)H(24)N(2)O(4), the benzimidazole ring system is almost planar, with a maximum deviation of 0.047 (1) Å and makes a dihedral angle of 88.44 (5)° with the attached benzene ring. In the crystal, mol­ecules form infinite chains along the b axis by way of inter­molecular O—H⋯N and C—H⋯O inter­actions. Weak C—H⋯π also contribute to the stabilization of the crystal structure. International Union of Crystallography 2010-04-10 /pmc/articles/PMC2979157/ /pubmed/21579111 http://dx.doi.org/10.1107/S1600536810011918 Text en © Arumugam et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Arumugam, Natarajan
Abdul Rahim, Aisyah Saad
Osman, Hasnah
Rosli, Mohd Mustaqim
Fun, Hoong-Kun
Ethyl 1-tert-butyl-2-(4-hydr­oxy-3-methoxy­phen­yl)-1H-benzimidazole-5-carboxyl­ate
title Ethyl 1-tert-butyl-2-(4-hydr­oxy-3-methoxy­phen­yl)-1H-benzimidazole-5-carboxyl­ate
title_full Ethyl 1-tert-butyl-2-(4-hydr­oxy-3-methoxy­phen­yl)-1H-benzimidazole-5-carboxyl­ate
title_fullStr Ethyl 1-tert-butyl-2-(4-hydr­oxy-3-methoxy­phen­yl)-1H-benzimidazole-5-carboxyl­ate
title_full_unstemmed Ethyl 1-tert-butyl-2-(4-hydr­oxy-3-methoxy­phen­yl)-1H-benzimidazole-5-carboxyl­ate
title_short Ethyl 1-tert-butyl-2-(4-hydr­oxy-3-methoxy­phen­yl)-1H-benzimidazole-5-carboxyl­ate
title_sort ethyl 1-tert-butyl-2-(4-hydr­oxy-3-methoxy­phen­yl)-1h-benzimidazole-5-carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979157/
https://www.ncbi.nlm.nih.gov/pubmed/21579111
http://dx.doi.org/10.1107/S1600536810011918
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