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2-(tert-Butoxy­carbonyl­amino)-6-(1,3-dioxo-1H-2,3-dihydro­benzo[de]isoquinolin-2-yl)hexa­noic acid

In the title naphthalimide derivative, C(23)H(26)N(2)O(6), the 1,8-naphthalimide system is essentially planar [maximum deviation = 0.0456 (16) Å]. A characteristic pattern of alternating long and short C—C bond lengths is observed in the 1,8-naphthalimide unit. The mean planes through the methyl car...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Goh, Jia Hao, Qiu, Zhenjun, Zhang, Yan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979163/
https://www.ncbi.nlm.nih.gov/pubmed/21579232
http://dx.doi.org/10.1107/S1600536810014935
Descripción
Sumario:In the title naphthalimide derivative, C(23)H(26)N(2)O(6), the 1,8-naphthalimide system is essentially planar [maximum deviation = 0.0456 (16) Å]. A characteristic pattern of alternating long and short C—C bond lengths is observed in the 1,8-naphthalimide unit. The mean planes through the methyl carbamate and acetic acid groups form dihedral angles of 42.30 (9) and 61.59 (9)°, respectively, with the 1,8-naphthalimide plane. In the crystal structure, inter­molecular O—H⋯O and C—H⋯O hydrogen bonds link neighbouring mol­ecules, forming R (2) (2)(9) hydrogen-bond ring motifs. These rings are further inter­connected by inter­molecular N—H⋯O and C—H⋯O hydrogen bonds into a three-dimensional supra­molecular network.