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2-(tert-Butoxycarbonylamino)-6-(1,3-dioxo-1H-2,3-dihydrobenzo[de]isoquinolin-2-yl)hexanoic acid
In the title naphthalimide derivative, C(23)H(26)N(2)O(6), the 1,8-naphthalimide system is essentially planar [maximum deviation = 0.0456 (16) Å]. A characteristic pattern of alternating long and short C—C bond lengths is observed in the 1,8-naphthalimide unit. The mean planes through the methyl car...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979163/ https://www.ncbi.nlm.nih.gov/pubmed/21579232 http://dx.doi.org/10.1107/S1600536810014935 |
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author | Fun, Hoong-Kun Goh, Jia Hao Qiu, Zhenjun Zhang, Yan |
author_facet | Fun, Hoong-Kun Goh, Jia Hao Qiu, Zhenjun Zhang, Yan |
author_sort | Fun, Hoong-Kun |
collection | PubMed |
description | In the title naphthalimide derivative, C(23)H(26)N(2)O(6), the 1,8-naphthalimide system is essentially planar [maximum deviation = 0.0456 (16) Å]. A characteristic pattern of alternating long and short C—C bond lengths is observed in the 1,8-naphthalimide unit. The mean planes through the methyl carbamate and acetic acid groups form dihedral angles of 42.30 (9) and 61.59 (9)°, respectively, with the 1,8-naphthalimide plane. In the crystal structure, intermolecular O—H⋯O and C—H⋯O hydrogen bonds link neighbouring molecules, forming R (2) (2)(9) hydrogen-bond ring motifs. These rings are further interconnected by intermolecular N—H⋯O and C—H⋯O hydrogen bonds into a three-dimensional supramolecular network. |
format | Text |
id | pubmed-2979163 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29791632010-12-30 2-(tert-Butoxycarbonylamino)-6-(1,3-dioxo-1H-2,3-dihydrobenzo[de]isoquinolin-2-yl)hexanoic acid Fun, Hoong-Kun Goh, Jia Hao Qiu, Zhenjun Zhang, Yan Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title naphthalimide derivative, C(23)H(26)N(2)O(6), the 1,8-naphthalimide system is essentially planar [maximum deviation = 0.0456 (16) Å]. A characteristic pattern of alternating long and short C—C bond lengths is observed in the 1,8-naphthalimide unit. The mean planes through the methyl carbamate and acetic acid groups form dihedral angles of 42.30 (9) and 61.59 (9)°, respectively, with the 1,8-naphthalimide plane. In the crystal structure, intermolecular O—H⋯O and C—H⋯O hydrogen bonds link neighbouring molecules, forming R (2) (2)(9) hydrogen-bond ring motifs. These rings are further interconnected by intermolecular N—H⋯O and C—H⋯O hydrogen bonds into a three-dimensional supramolecular network. International Union of Crystallography 2010-04-28 /pmc/articles/PMC2979163/ /pubmed/21579232 http://dx.doi.org/10.1107/S1600536810014935 Text en © Fun et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Fun, Hoong-Kun Goh, Jia Hao Qiu, Zhenjun Zhang, Yan 2-(tert-Butoxycarbonylamino)-6-(1,3-dioxo-1H-2,3-dihydrobenzo[de]isoquinolin-2-yl)hexanoic acid |
title | 2-(tert-Butoxycarbonylamino)-6-(1,3-dioxo-1H-2,3-dihydrobenzo[de]isoquinolin-2-yl)hexanoic acid |
title_full | 2-(tert-Butoxycarbonylamino)-6-(1,3-dioxo-1H-2,3-dihydrobenzo[de]isoquinolin-2-yl)hexanoic acid |
title_fullStr | 2-(tert-Butoxycarbonylamino)-6-(1,3-dioxo-1H-2,3-dihydrobenzo[de]isoquinolin-2-yl)hexanoic acid |
title_full_unstemmed | 2-(tert-Butoxycarbonylamino)-6-(1,3-dioxo-1H-2,3-dihydrobenzo[de]isoquinolin-2-yl)hexanoic acid |
title_short | 2-(tert-Butoxycarbonylamino)-6-(1,3-dioxo-1H-2,3-dihydrobenzo[de]isoquinolin-2-yl)hexanoic acid |
title_sort | 2-(tert-butoxycarbonylamino)-6-(1,3-dioxo-1h-2,3-dihydrobenzo[de]isoquinolin-2-yl)hexanoic acid |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979163/ https://www.ncbi.nlm.nih.gov/pubmed/21579232 http://dx.doi.org/10.1107/S1600536810014935 |
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