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2-(tert-Butoxy­carbonyl­amino)-6-(1,3-dioxo-1H-2,3-dihydro­benzo[de]isoquinolin-2-yl)hexa­noic acid

In the title naphthalimide derivative, C(23)H(26)N(2)O(6), the 1,8-naphthalimide system is essentially planar [maximum deviation = 0.0456 (16) Å]. A characteristic pattern of alternating long and short C—C bond lengths is observed in the 1,8-naphthalimide unit. The mean planes through the methyl car...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Goh, Jia Hao, Qiu, Zhenjun, Zhang, Yan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979163/
https://www.ncbi.nlm.nih.gov/pubmed/21579232
http://dx.doi.org/10.1107/S1600536810014935
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author Fun, Hoong-Kun
Goh, Jia Hao
Qiu, Zhenjun
Zhang, Yan
author_facet Fun, Hoong-Kun
Goh, Jia Hao
Qiu, Zhenjun
Zhang, Yan
author_sort Fun, Hoong-Kun
collection PubMed
description In the title naphthalimide derivative, C(23)H(26)N(2)O(6), the 1,8-naphthalimide system is essentially planar [maximum deviation = 0.0456 (16) Å]. A characteristic pattern of alternating long and short C—C bond lengths is observed in the 1,8-naphthalimide unit. The mean planes through the methyl carbamate and acetic acid groups form dihedral angles of 42.30 (9) and 61.59 (9)°, respectively, with the 1,8-naphthalimide plane. In the crystal structure, inter­molecular O—H⋯O and C—H⋯O hydrogen bonds link neighbouring mol­ecules, forming R (2) (2)(9) hydrogen-bond ring motifs. These rings are further inter­connected by inter­molecular N—H⋯O and C—H⋯O hydrogen bonds into a three-dimensional supra­molecular network.
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spelling pubmed-29791632010-12-30 2-(tert-Butoxy­carbonyl­amino)-6-(1,3-dioxo-1H-2,3-dihydro­benzo[de]isoquinolin-2-yl)hexa­noic acid Fun, Hoong-Kun Goh, Jia Hao Qiu, Zhenjun Zhang, Yan Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title naphthalimide derivative, C(23)H(26)N(2)O(6), the 1,8-naphthalimide system is essentially planar [maximum deviation = 0.0456 (16) Å]. A characteristic pattern of alternating long and short C—C bond lengths is observed in the 1,8-naphthalimide unit. The mean planes through the methyl carbamate and acetic acid groups form dihedral angles of 42.30 (9) and 61.59 (9)°, respectively, with the 1,8-naphthalimide plane. In the crystal structure, inter­molecular O—H⋯O and C—H⋯O hydrogen bonds link neighbouring mol­ecules, forming R (2) (2)(9) hydrogen-bond ring motifs. These rings are further inter­connected by inter­molecular N—H⋯O and C—H⋯O hydrogen bonds into a three-dimensional supra­molecular network. International Union of Crystallography 2010-04-28 /pmc/articles/PMC2979163/ /pubmed/21579232 http://dx.doi.org/10.1107/S1600536810014935 Text en © Fun et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Goh, Jia Hao
Qiu, Zhenjun
Zhang, Yan
2-(tert-Butoxy­carbonyl­amino)-6-(1,3-dioxo-1H-2,3-dihydro­benzo[de]isoquinolin-2-yl)hexa­noic acid
title 2-(tert-Butoxy­carbonyl­amino)-6-(1,3-dioxo-1H-2,3-dihydro­benzo[de]isoquinolin-2-yl)hexa­noic acid
title_full 2-(tert-Butoxy­carbonyl­amino)-6-(1,3-dioxo-1H-2,3-dihydro­benzo[de]isoquinolin-2-yl)hexa­noic acid
title_fullStr 2-(tert-Butoxy­carbonyl­amino)-6-(1,3-dioxo-1H-2,3-dihydro­benzo[de]isoquinolin-2-yl)hexa­noic acid
title_full_unstemmed 2-(tert-Butoxy­carbonyl­amino)-6-(1,3-dioxo-1H-2,3-dihydro­benzo[de]isoquinolin-2-yl)hexa­noic acid
title_short 2-(tert-Butoxy­carbonyl­amino)-6-(1,3-dioxo-1H-2,3-dihydro­benzo[de]isoquinolin-2-yl)hexa­noic acid
title_sort 2-(tert-butoxy­carbonyl­amino)-6-(1,3-dioxo-1h-2,3-dihydro­benzo[de]isoquinolin-2-yl)hexa­noic acid
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979163/
https://www.ncbi.nlm.nih.gov/pubmed/21579232
http://dx.doi.org/10.1107/S1600536810014935
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