7-Bromo-2-(4-fluoro­phen­yl)-1-(methyl­sulfin­yl)naphtho[2,1-b]furan

In the title compound, C(19)H(12)BrFO(2)S, the O atom and the methyl group of the methyl­sulfinyl substituent lie on opposite sides of the plane through the naphthofuran fragment. The 4-fluoro­phenyl ring is rotated out of the naphthofuran plane, making a dihedral angle of 41.65 (7)°. In the crystal...

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Detalles Bibliográficos
Autores principales: Choi, Hong Dae, Seo, Pil Ja, Son, Byeng Wha, Lee, Uk
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979164/
https://www.ncbi.nlm.nih.gov/pubmed/21579076
http://dx.doi.org/10.1107/S1600536810011645
Descripción
Sumario:In the title compound, C(19)H(12)BrFO(2)S, the O atom and the methyl group of the methyl­sulfinyl substituent lie on opposite sides of the plane through the naphthofuran fragment. The 4-fluoro­phenyl ring is rotated out of the naphthofuran plane, making a dihedral angle of 41.65 (7)°. In the crystal, mol­ecules are linked by weak inter­molecular C—H⋯O and C—H⋯π inter­actions, and a short Br⋯F contact [3.046 (2) Å] occurs. The O atom of the sulfinyl group is disordered over two positions, with refined site-occupancy factors of 0.912 (4) and 0.088 (4).

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