Bis­[4,4′-(propane-1,3-di­yl)­dipiperidin­ium] β-octa­molybdate(VI)

The title compound, bis­[4,4′-(propane-1,3-di­yl)­dipiperidin­ium] β-octa­molybdate(VI), (C(13)H(28)N(2))(2)[Mo(8)O(26)], was produced by hydro­thermal reaction of an acidified aqueous solution of Na(2)MoO(4)·2H(2)O and 4,4′-trimethyl­ene­dipiperidine (L). The structure of the title compound consist...

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Detalles Bibliográficos
Autores principales: Driss, Mohamed, Ksiksi, Rekaya, Ben Amor, Fatma, Zid, Mohamed Faouzi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979165/
https://www.ncbi.nlm.nih.gov/pubmed/21579027
http://dx.doi.org/10.1107/S1600536810013632
Descripción
Sumario:The title compound, bis­[4,4′-(propane-1,3-di­yl)­dipiperidin­ium] β-octa­molybdate(VI), (C(13)H(28)N(2))(2)[Mo(8)O(26)], was produced by hydro­thermal reaction of an acidified aqueous solution of Na(2)MoO(4)·2H(2)O and 4,4′-trimethyl­ene­dipiperidine (L). The structure of the title compound consists of β-octa­molybdate(VI) anion clusters and protonated [H(2) L](2+) cations. The octa­molybdate anion is located around an inversion center. N—H⋯O hydrogen bonds between the cations and anions ensure the cohesion of the structure and result in a three-dimensional network.

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