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Tetrakis(μ-2-methylbenzoato-κ(2) O:O′)bis[(methanol-κO)copper(II)]
In the title compound, [Cu(2)(C(8)H(7)O(2))(4)(CH(3)OH)(2)], the Cu—O bond distances are in the range 1.943 (2)–2.149 (2) Å within a sligthly distorted square-pyramidal coordination. The Cu⋯Cu separation is 2.5912 (4) Å. In the crystal, the molecules are linked into polymeric chains propagating in...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979172/ https://www.ncbi.nlm.nih.gov/pubmed/21579022 http://dx.doi.org/10.1107/S1600536810013322 |
Sumario: | In the title compound, [Cu(2)(C(8)H(7)O(2))(4)(CH(3)OH)(2)], the Cu—O bond distances are in the range 1.943 (2)–2.149 (2) Å within a sligthly distorted square-pyramidal coordination. The Cu⋯Cu separation is 2.5912 (4) Å. In the crystal, the molecules are linked into polymeric chains propagating in [001] by intermolecular O—H⋯O hydrogen bonds and C—H⋯π interactions. |
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