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Tetrakis(μ-2-methylbenzoato-κ(2) O:O′)bis[(methanol-κO)copper(II)]
In the title compound, [Cu(2)(C(8)H(7)O(2))(4)(CH(3)OH)(2)], the Cu—O bond distances are in the range 1.943 (2)–2.149 (2) Å within a sligthly distorted square-pyramidal coordination. The Cu⋯Cu separation is 2.5912 (4) Å. In the crystal, the molecules are linked into polymeric chains propagating in...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979172/ https://www.ncbi.nlm.nih.gov/pubmed/21579022 http://dx.doi.org/10.1107/S1600536810013322 |
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author | Danish, Muhammad Saleem, Iram Tahir, M. Nawaz Ahmad, Nazir Raza, Abdur Rauf |
author_facet | Danish, Muhammad Saleem, Iram Tahir, M. Nawaz Ahmad, Nazir Raza, Abdur Rauf |
author_sort | Danish, Muhammad |
collection | PubMed |
description | In the title compound, [Cu(2)(C(8)H(7)O(2))(4)(CH(3)OH)(2)], the Cu—O bond distances are in the range 1.943 (2)–2.149 (2) Å within a sligthly distorted square-pyramidal coordination. The Cu⋯Cu separation is 2.5912 (4) Å. In the crystal, the molecules are linked into polymeric chains propagating in [001] by intermolecular O—H⋯O hydrogen bonds and C—H⋯π interactions. |
format | Text |
id | pubmed-2979172 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29791722010-12-30 Tetrakis(μ-2-methylbenzoato-κ(2) O:O′)bis[(methanol-κO)copper(II)] Danish, Muhammad Saleem, Iram Tahir, M. Nawaz Ahmad, Nazir Raza, Abdur Rauf Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(2)(C(8)H(7)O(2))(4)(CH(3)OH)(2)], the Cu—O bond distances are in the range 1.943 (2)–2.149 (2) Å within a sligthly distorted square-pyramidal coordination. The Cu⋯Cu separation is 2.5912 (4) Å. In the crystal, the molecules are linked into polymeric chains propagating in [001] by intermolecular O—H⋯O hydrogen bonds and C—H⋯π interactions. International Union of Crystallography 2010-04-17 /pmc/articles/PMC2979172/ /pubmed/21579022 http://dx.doi.org/10.1107/S1600536810013322 Text en © Danish et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Danish, Muhammad Saleem, Iram Tahir, M. Nawaz Ahmad, Nazir Raza, Abdur Rauf Tetrakis(μ-2-methylbenzoato-κ(2) O:O′)bis[(methanol-κO)copper(II)] |
title | Tetrakis(μ-2-methylbenzoato-κ(2)
O:O′)bis[(methanol-κO)copper(II)] |
title_full | Tetrakis(μ-2-methylbenzoato-κ(2)
O:O′)bis[(methanol-κO)copper(II)] |
title_fullStr | Tetrakis(μ-2-methylbenzoato-κ(2)
O:O′)bis[(methanol-κO)copper(II)] |
title_full_unstemmed | Tetrakis(μ-2-methylbenzoato-κ(2)
O:O′)bis[(methanol-κO)copper(II)] |
title_short | Tetrakis(μ-2-methylbenzoato-κ(2)
O:O′)bis[(methanol-κO)copper(II)] |
title_sort | tetrakis(μ-2-methylbenzoato-κ(2)
o:o′)bis[(methanol-κo)copper(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979172/ https://www.ncbi.nlm.nih.gov/pubmed/21579022 http://dx.doi.org/10.1107/S1600536810013322 |
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