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Bis[(1-ammonioethane-1,1-diyl)diphosphonato-κ(2) O,O′]diaquanickel(II) nonahydrate
The title compound, [Ni(C(2)H(8)NO(6)P(2))(2)(H(2)O)(2)]·9H(2)O, exhibits a slightly distorted octahedral coordination environment around the Ni(II) atom. It contains two molecules of 1-aminoethylidenediphosphonic acid in the zwitterionic form, coordinated via O atoms from two phosphonate gr...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979174/ https://www.ncbi.nlm.nih.gov/pubmed/21579065 http://dx.doi.org/10.1107/S160053681001531X |
Sumario: | The title compound, [Ni(C(2)H(8)NO(6)P(2))(2)(H(2)O)(2)]·9H(2)O, exhibits a slightly distorted octahedral coordination environment around the Ni(II) atom. It contains two molecules of 1-aminoethylidenediphosphonic acid in the zwitterionic form, coordinated via O atoms from two phosphonate groups and creating two six-membered chelate rings. Two water molecules in cis positions complete the coordination environment of the Ni(II) atom. The title compound contains nine partly disordered solvent water molecules, which create a three-dimensional network of strong O—H⋯O and N—H⋯O hydrogen bonds. |
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