[O-Ethyl (Z)-N-(2-chloro­phen­yl)thio­carbamato-κS](tricyclo­hexyl­phosphine-κP)gold(I)

The title compound, [Au(C(9)H(9)ClNOS)(C(18)H(33)P)], features a slightly distorted linear coordination geometry for the Au atom defined by a S,P-donor set [S—Au—P = 177.62 (5)°]. The distortion is ascribed to the close approach of the O atom, which forms an intra­molecular contact of 2.970 (5) Å. D...

Descripción completa

Detalles Bibliográficos
Autores principales: Tadbuppa, Primjira P., Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979177/
https://www.ncbi.nlm.nih.gov/pubmed/21578999
http://dx.doi.org/10.1107/S160053681001189X
Descripción
Sumario:The title compound, [Au(C(9)H(9)ClNOS)(C(18)H(33)P)], features a slightly distorted linear coordination geometry for the Au atom defined by a S,P-donor set [S—Au—P = 177.62 (5)°]. The distortion is ascribed to the close approach of the O atom, which forms an intra­molecular contact of 2.970 (5) Å. Disorder was found in the structure with two positions of equal weight being resolved for the C atoms comprising the eth­oxy group.

Ejemplares similares