[O-Ethyl (Z)-N-(2-chloro­phen­yl)thio­carbamato-κS](tricyclo­hexyl­phosphine-κP)gold(I)

The title compound, [Au(C(9)H(9)ClNOS)(C(18)H(33)P)], features a slightly distorted linear coordination geometry for the Au atom defined by a S,P-donor set [S—Au—P = 177.62 (5)°]. The distortion is ascribed to the close approach of the O atom, which forms an intra­molecular contact of 2.970 (5) Å. D...

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Detalles Bibliográficos
Autores principales: Tadbuppa, Primjira P., Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979177/
https://www.ncbi.nlm.nih.gov/pubmed/21578999
http://dx.doi.org/10.1107/S160053681001189X
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author Tadbuppa, Primjira P.
Tiekink, Edward R. T.
author_facet Tadbuppa, Primjira P.
Tiekink, Edward R. T.
author_sort Tadbuppa, Primjira P.
collection PubMed
description The title compound, [Au(C(9)H(9)ClNOS)(C(18)H(33)P)], features a slightly distorted linear coordination geometry for the Au atom defined by a S,P-donor set [S—Au—P = 177.62 (5)°]. The distortion is ascribed to the close approach of the O atom, which forms an intra­molecular contact of 2.970 (5) Å. Disorder was found in the structure with two positions of equal weight being resolved for the C atoms comprising the eth­oxy group.
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spelling pubmed-29791772010-12-30 [O-Ethyl (Z)-N-(2-chloro­phen­yl)thio­carbamato-κS](tricyclo­hexyl­phosphine-κP)gold(I) Tadbuppa, Primjira P. Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Au(C(9)H(9)ClNOS)(C(18)H(33)P)], features a slightly distorted linear coordination geometry for the Au atom defined by a S,P-donor set [S—Au—P = 177.62 (5)°]. The distortion is ascribed to the close approach of the O atom, which forms an intra­molecular contact of 2.970 (5) Å. Disorder was found in the structure with two positions of equal weight being resolved for the C atoms comprising the eth­oxy group. International Union of Crystallography 2010-04-10 /pmc/articles/PMC2979177/ /pubmed/21578999 http://dx.doi.org/10.1107/S160053681001189X Text en © Tadbuppa and Tiekink 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tadbuppa, Primjira P.
Tiekink, Edward R. T.
[O-Ethyl (Z)-N-(2-chloro­phen­yl)thio­carbamato-κS](tricyclo­hexyl­phosphine-κP)gold(I)
title [O-Ethyl (Z)-N-(2-chloro­phen­yl)thio­carbamato-κS](tricyclo­hexyl­phosphine-κP)gold(I)
title_full [O-Ethyl (Z)-N-(2-chloro­phen­yl)thio­carbamato-κS](tricyclo­hexyl­phosphine-κP)gold(I)
title_fullStr [O-Ethyl (Z)-N-(2-chloro­phen­yl)thio­carbamato-κS](tricyclo­hexyl­phosphine-κP)gold(I)
title_full_unstemmed [O-Ethyl (Z)-N-(2-chloro­phen­yl)thio­carbamato-κS](tricyclo­hexyl­phosphine-κP)gold(I)
title_short [O-Ethyl (Z)-N-(2-chloro­phen­yl)thio­carbamato-κS](tricyclo­hexyl­phosphine-κP)gold(I)
title_sort [o-ethyl (z)-n-(2-chloro­phen­yl)thio­carbamato-κs](tricyclo­hexyl­phosphine-κp)gold(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979177/
https://www.ncbi.nlm.nih.gov/pubmed/21578999
http://dx.doi.org/10.1107/S160053681001189X
work_keys_str_mv AT tadbuppaprimjirap oethylzn2chlorophenylthiocarbamatokstricyclohexylphosphinekpgoldi
AT tiekinkedwardrt oethylzn2chlorophenylthiocarbamatokstricyclohexylphosphinekpgoldi

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