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Di-μ-thio­cyanato-κ(4) N:N-bis­({5-meth­oxy-2-[3-(methyl­amino)propyl­imino­meth­yl]phenolato-κ(3) O (1),N,N′}copper(II))

The title thio­cyanate-bridged dinuclear copper(II) complex, [Cu(2)(C(12)H(17)N(2)O(2))(2)(NCS)(2)], possesses crystallographic inversion symmetry. Each Cu(II) atom is five-coordinated by one imine N, one amine N and one phenolate O atom of the Schiff base ligand, and by two N atoms from two bridgin...

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Detalles Bibliográficos
Autores principales: Wang, Nong, Xue, Rui, Li, Bo, Yang, Yu-Ping, Cao, Min
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979178/
https://www.ncbi.nlm.nih.gov/pubmed/21579071
http://dx.doi.org/10.1107/S1600536810015564
Descripción
Sumario:The title thio­cyanate-bridged dinuclear copper(II) complex, [Cu(2)(C(12)H(17)N(2)O(2))(2)(NCS)(2)], possesses crystallographic inversion symmetry. Each Cu(II) atom is five-coordinated by one imine N, one amine N and one phenolate O atom of the Schiff base ligand, and by two N atoms from two bridging thio­cyanate ligands, forming a square-pyramidal geometry. Beside the two thio­cyanate bridges, there are two intra­molecular N—H⋯O hydrogen bonds, which further link the two Cu(C(12)H(17)N(2)O(2))(NCS) units. The Cu⋯Cu separation is 3.261 (2) Å. Parts of the methylaminopropylimino segment are disordered over two sites with occupancies of 0.669(9) and 0.331(9).