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Di-μ-thiocyanato-κ(4) N:N-bis({5-methoxy-2-[3-(methylamino)propyliminomethyl]phenolato-κ(3) O (1),N,N′}copper(II))
The title thiocyanate-bridged dinuclear copper(II) complex, [Cu(2)(C(12)H(17)N(2)O(2))(2)(NCS)(2)], possesses crystallographic inversion symmetry. Each Cu(II) atom is five-coordinated by one imine N, one amine N and one phenolate O atom of the Schiff base ligand, and by two N atoms from two bridgin...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979178/ https://www.ncbi.nlm.nih.gov/pubmed/21579071 http://dx.doi.org/10.1107/S1600536810015564 |
Sumario: | The title thiocyanate-bridged dinuclear copper(II) complex, [Cu(2)(C(12)H(17)N(2)O(2))(2)(NCS)(2)], possesses crystallographic inversion symmetry. Each Cu(II) atom is five-coordinated by one imine N, one amine N and one phenolate O atom of the Schiff base ligand, and by two N atoms from two bridging thiocyanate ligands, forming a square-pyramidal geometry. Beside the two thiocyanate bridges, there are two intramolecular N—H⋯O hydrogen bonds, which further link the two Cu(C(12)H(17)N(2)O(2))(NCS) units. The Cu⋯Cu separation is 3.261 (2) Å. Parts of the methylaminopropylimino segment are disordered over two sites with occupancies of 0.669(9) and 0.331(9). |
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