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Di-μ-thiocyanato-κ(4) N:N-bis({5-methoxy-2-[3-(methylamino)propyliminomethyl]phenolato-κ(3) O (1),N,N′}copper(II))
The title thiocyanate-bridged dinuclear copper(II) complex, [Cu(2)(C(12)H(17)N(2)O(2))(2)(NCS)(2)], possesses crystallographic inversion symmetry. Each Cu(II) atom is five-coordinated by one imine N, one amine N and one phenolate O atom of the Schiff base ligand, and by two N atoms from two bridgin...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979178/ https://www.ncbi.nlm.nih.gov/pubmed/21579071 http://dx.doi.org/10.1107/S1600536810015564 |
| _version_ | 1782191361966997504 |
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| author | Wang, Nong Xue, Rui Li, Bo Yang, Yu-Ping Cao, Min |
| author_facet | Wang, Nong Xue, Rui Li, Bo Yang, Yu-Ping Cao, Min |
| author_sort | Wang, Nong |
| collection | PubMed |
| description | The title thiocyanate-bridged dinuclear copper(II) complex, [Cu(2)(C(12)H(17)N(2)O(2))(2)(NCS)(2)], possesses crystallographic inversion symmetry. Each Cu(II) atom is five-coordinated by one imine N, one amine N and one phenolate O atom of the Schiff base ligand, and by two N atoms from two bridging thiocyanate ligands, forming a square-pyramidal geometry. Beside the two thiocyanate bridges, there are two intramolecular N—H⋯O hydrogen bonds, which further link the two Cu(C(12)H(17)N(2)O(2))(NCS) units. The Cu⋯Cu separation is 3.261 (2) Å. Parts of the methylaminopropylimino segment are disordered over two sites with occupancies of 0.669(9) and 0.331(9). |
| format | Text |
| id | pubmed-2979178 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29791782010-12-30 Di-μ-thiocyanato-κ(4) N:N-bis({5-methoxy-2-[3-(methylamino)propyliminomethyl]phenolato-κ(3) O (1),N,N′}copper(II)) Wang, Nong Xue, Rui Li, Bo Yang, Yu-Ping Cao, Min Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title thiocyanate-bridged dinuclear copper(II) complex, [Cu(2)(C(12)H(17)N(2)O(2))(2)(NCS)(2)], possesses crystallographic inversion symmetry. Each Cu(II) atom is five-coordinated by one imine N, one amine N and one phenolate O atom of the Schiff base ligand, and by two N atoms from two bridging thiocyanate ligands, forming a square-pyramidal geometry. Beside the two thiocyanate bridges, there are two intramolecular N—H⋯O hydrogen bonds, which further link the two Cu(C(12)H(17)N(2)O(2))(NCS) units. The Cu⋯Cu separation is 3.261 (2) Å. Parts of the methylaminopropylimino segment are disordered over two sites with occupancies of 0.669(9) and 0.331(9). International Union of Crystallography 2010-04-30 /pmc/articles/PMC2979178/ /pubmed/21579071 http://dx.doi.org/10.1107/S1600536810015564 Text en © Wang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Wang, Nong Xue, Rui Li, Bo Yang, Yu-Ping Cao, Min Di-μ-thiocyanato-κ(4) N:N-bis({5-methoxy-2-[3-(methylamino)propyliminomethyl]phenolato-κ(3) O (1),N,N′}copper(II)) |
| title | Di-μ-thiocyanato-κ(4)
N:N-bis({5-methoxy-2-[3-(methylamino)propyliminomethyl]phenolato-κ(3)
O
(1),N,N′}copper(II)) |
| title_full | Di-μ-thiocyanato-κ(4)
N:N-bis({5-methoxy-2-[3-(methylamino)propyliminomethyl]phenolato-κ(3)
O
(1),N,N′}copper(II)) |
| title_fullStr | Di-μ-thiocyanato-κ(4)
N:N-bis({5-methoxy-2-[3-(methylamino)propyliminomethyl]phenolato-κ(3)
O
(1),N,N′}copper(II)) |
| title_full_unstemmed | Di-μ-thiocyanato-κ(4)
N:N-bis({5-methoxy-2-[3-(methylamino)propyliminomethyl]phenolato-κ(3)
O
(1),N,N′}copper(II)) |
| title_short | Di-μ-thiocyanato-κ(4)
N:N-bis({5-methoxy-2-[3-(methylamino)propyliminomethyl]phenolato-κ(3)
O
(1),N,N′}copper(II)) |
| title_sort | di-μ-thiocyanato-κ(4)
n:n-bis({5-methoxy-2-[3-(methylamino)propyliminomethyl]phenolato-κ(3)
o
(1),n,n′}copper(ii)) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979178/ https://www.ncbi.nlm.nih.gov/pubmed/21579071 http://dx.doi.org/10.1107/S1600536810015564 |
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