3,3′-(5,5,7,12,12,14-Hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­decane-1,8-diyl)di­propanonitrile methanol disolvate

The asymmetric unit of the title compound, C(22)H(42)N(6)·2CH(4)O, comprises one half of a 14-membered tetra­azacyclo­tetra­decane macrocycle with cyano­ethyl substituents on one of the N atoms and a methanol solvent mol­ecule. The macrocycle lies about an inversion centre. The cyano­ethyl substitue...

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Detalles Bibliográficos
Autores principales: Hao, Cheng-Jun, Zhang, Yan-Hua
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979179/
https://www.ncbi.nlm.nih.gov/pubmed/21579142
http://dx.doi.org/10.1107/S1600536810013073
Descripción
Sumario:The asymmetric unit of the title compound, C(22)H(42)N(6)·2CH(4)O, comprises one half of a 14-membered tetra­azacyclo­tetra­decane macrocycle with cyano­ethyl substituents on one of the N atoms and a methanol solvent mol­ecule. The macrocycle lies about an inversion centre. The cyano­ethyl substituents are oriented so that the cyano groups lie over opposite faces of the central cavity of the macrocycle. The methanol solvate mol­ecules lie away from the cavity of the macrocycle and are linked to the macrocycles via O—H⋯N hydrogen bonds.

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