3,3′-(5,5,7,12,12,14-Hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­decane-1,8-diyl)di­propanonitrile methanol disolvate

The asymmetric unit of the title compound, C(22)H(42)N(6)·2CH(4)O, comprises one half of a 14-membered tetra­azacyclo­tetra­decane macrocycle with cyano­ethyl substituents on one of the N atoms and a methanol solvent mol­ecule. The macrocycle lies about an inversion centre. The cyano­ethyl substitue...

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Detalles Bibliográficos
Autores principales: Hao, Cheng-Jun, Zhang, Yan-Hua
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979179/
https://www.ncbi.nlm.nih.gov/pubmed/21579142
http://dx.doi.org/10.1107/S1600536810013073
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author Hao, Cheng-Jun
Zhang, Yan-Hua
author_facet Hao, Cheng-Jun
Zhang, Yan-Hua
author_sort Hao, Cheng-Jun
collection PubMed
description The asymmetric unit of the title compound, C(22)H(42)N(6)·2CH(4)O, comprises one half of a 14-membered tetra­azacyclo­tetra­decane macrocycle with cyano­ethyl substituents on one of the N atoms and a methanol solvent mol­ecule. The macrocycle lies about an inversion centre. The cyano­ethyl substituents are oriented so that the cyano groups lie over opposite faces of the central cavity of the macrocycle. The methanol solvate mol­ecules lie away from the cavity of the macrocycle and are linked to the macrocycles via O—H⋯N hydrogen bonds.
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spelling pubmed-29791792010-12-30 3,3′-(5,5,7,12,12,14-Hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­decane-1,8-diyl)di­propanonitrile methanol disolvate Hao, Cheng-Jun Zhang, Yan-Hua Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(22)H(42)N(6)·2CH(4)O, comprises one half of a 14-membered tetra­azacyclo­tetra­decane macrocycle with cyano­ethyl substituents on one of the N atoms and a methanol solvent mol­ecule. The macrocycle lies about an inversion centre. The cyano­ethyl substituents are oriented so that the cyano groups lie over opposite faces of the central cavity of the macrocycle. The methanol solvate mol­ecules lie away from the cavity of the macrocycle and are linked to the macrocycles via O—H⋯N hydrogen bonds. International Union of Crystallography 2010-04-17 /pmc/articles/PMC2979179/ /pubmed/21579142 http://dx.doi.org/10.1107/S1600536810013073 Text en © Hao and Zhang 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Hao, Cheng-Jun
Zhang, Yan-Hua
3,3′-(5,5,7,12,12,14-Hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­decane-1,8-diyl)di­propanonitrile methanol disolvate
title 3,3′-(5,5,7,12,12,14-Hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­decane-1,8-diyl)di­propanonitrile methanol disolvate
title_full 3,3′-(5,5,7,12,12,14-Hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­decane-1,8-diyl)di­propanonitrile methanol disolvate
title_fullStr 3,3′-(5,5,7,12,12,14-Hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­decane-1,8-diyl)di­propanonitrile methanol disolvate
title_full_unstemmed 3,3′-(5,5,7,12,12,14-Hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­decane-1,8-diyl)di­propanonitrile methanol disolvate
title_short 3,3′-(5,5,7,12,12,14-Hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­decane-1,8-diyl)di­propanonitrile methanol disolvate
title_sort 3,3′-(5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­decane-1,8-diyl)di­propanonitrile methanol disolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979179/
https://www.ncbi.nlm.nih.gov/pubmed/21579142
http://dx.doi.org/10.1107/S1600536810013073
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AT zhangyanhua 33557121214hexamethyl14811tetraazacyclotetradecane18diyldipropanonitrilemethanoldisolvate

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