Tetra­kis(di-4-pyridylsulfane)dinitratocopper(II)

In the title complex, [Cu(NO(3))(2)(C(10)H(8)N(2)S)(4)], the Cu(II) atom (site symmetry [Image: see text]) is coordinated by two monodentate nitrate ions and two monodentate di-4-pyridylsulfane ligands, resulting in a slightly distorted trans-arranged CuO(2)N(4) octa­hedral geometry. Intra­molecular...

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Detalles Bibliográficos
Autores principales: Gao, Rong-Hua, Yang, Li-Li
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979183/
https://www.ncbi.nlm.nih.gov/pubmed/21578992
http://dx.doi.org/10.1107/S1600536810011414
Descripción
Sumario:In the title complex, [Cu(NO(3))(2)(C(10)H(8)N(2)S)(4)], the Cu(II) atom (site symmetry [Image: see text]) is coordinated by two monodentate nitrate ions and two monodentate di-4-pyridylsulfane ligands, resulting in a slightly distorted trans-arranged CuO(2)N(4) octa­hedral geometry. Intra­molecular C—H⋯O hydrogen bonds are present. In the crystal, adjacent mol­ecules are linked via C—H⋯N hydrogen bonds into chains parallel to the a axis. Inter­molecular C—H⋯O inter­actions also occur.

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