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Tetrakis(di-4-pyridylsulfane)dinitratocopper(II)
In the title complex, [Cu(NO(3))(2)(C(10)H(8)N(2)S)(4)], the Cu(II) atom (site symmetry [Image: see text]) is coordinated by two monodentate nitrate ions and two monodentate di-4-pyridylsulfane ligands, resulting in a slightly distorted trans-arranged CuO(2)N(4) octahedral geometry. Intramolecular...
| Autores principales: | , |
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979183/ https://www.ncbi.nlm.nih.gov/pubmed/21578992 http://dx.doi.org/10.1107/S1600536810011414 |
| _version_ | 1782191363196977152 |
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| author | Gao, Rong-Hua Yang, Li-Li |
| author_facet | Gao, Rong-Hua Yang, Li-Li |
| author_sort | Gao, Rong-Hua |
| collection | PubMed |
| description | In the title complex, [Cu(NO(3))(2)(C(10)H(8)N(2)S)(4)], the Cu(II) atom (site symmetry [Image: see text]) is coordinated by two monodentate nitrate ions and two monodentate di-4-pyridylsulfane ligands, resulting in a slightly distorted trans-arranged CuO(2)N(4) octahedral geometry. Intramolecular C—H⋯O hydrogen bonds are present. In the crystal, adjacent molecules are linked via C—H⋯N hydrogen bonds into chains parallel to the a axis. Intermolecular C—H⋯O interactions also occur. |
| format | Text |
| id | pubmed-2979183 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29791832010-12-30 Tetrakis(di-4-pyridylsulfane)dinitratocopper(II) Gao, Rong-Hua Yang, Li-Li Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(NO(3))(2)(C(10)H(8)N(2)S)(4)], the Cu(II) atom (site symmetry [Image: see text]) is coordinated by two monodentate nitrate ions and two monodentate di-4-pyridylsulfane ligands, resulting in a slightly distorted trans-arranged CuO(2)N(4) octahedral geometry. Intramolecular C—H⋯O hydrogen bonds are present. In the crystal, adjacent molecules are linked via C—H⋯N hydrogen bonds into chains parallel to the a axis. Intermolecular C—H⋯O interactions also occur. International Union of Crystallography 2010-04-02 /pmc/articles/PMC2979183/ /pubmed/21578992 http://dx.doi.org/10.1107/S1600536810011414 Text en © Gao and Yang 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Gao, Rong-Hua Yang, Li-Li Tetrakis(di-4-pyridylsulfane)dinitratocopper(II) |
| title | Tetrakis(di-4-pyridylsulfane)dinitratocopper(II) |
| title_full | Tetrakis(di-4-pyridylsulfane)dinitratocopper(II) |
| title_fullStr | Tetrakis(di-4-pyridylsulfane)dinitratocopper(II) |
| title_full_unstemmed | Tetrakis(di-4-pyridylsulfane)dinitratocopper(II) |
| title_short | Tetrakis(di-4-pyridylsulfane)dinitratocopper(II) |
| title_sort | tetrakis(di-4-pyridylsulfane)dinitratocopper(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979183/ https://www.ncbi.nlm.nih.gov/pubmed/21578992 http://dx.doi.org/10.1107/S1600536810011414 |
| work_keys_str_mv | AT gaoronghua tetrakisdi4pyridylsulfanedinitratocopperii AT yanglili tetrakisdi4pyridylsulfanedinitratocopperii |