Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κ(2) O,O′)zinc(II) propane-1,3-diol solvate

In the title compound, [Zn(SO(4))(C(12)H(8)N(2))(2)]·C(3)H(8)O(2), the Zn(2+) ion (site symmetry 2) is coordinated by two chelating 1,10-phenanthroline ligands and an O,O′-bidentate sulfate ion (S site symmetry 2), resulting in a distorted cis-ZnO(2)N(4) octa­hedral geometry for the metal ion. The c...

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Detalles Bibliográficos
Autores principales: Cui, Jiang-Dong, Zhong, Kai-Long, Liu, Yan-Yun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979185/
https://www.ncbi.nlm.nih.gov/pubmed/21579046
http://dx.doi.org/10.1107/S1600536810014194
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author Cui, Jiang-Dong
Zhong, Kai-Long
Liu, Yan-Yun
author_facet Cui, Jiang-Dong
Zhong, Kai-Long
Liu, Yan-Yun
author_sort Cui, Jiang-Dong
collection PubMed
description In the title compound, [Zn(SO(4))(C(12)H(8)N(2))(2)]·C(3)H(8)O(2), the Zn(2+) ion (site symmetry 2) is coordinated by two chelating 1,10-phenanthroline ligands and an O,O′-bidentate sulfate ion (S site symmetry 2), resulting in a distorted cis-ZnO(2)N(4) octa­hedral geometry for the metal ion. The complete propane-1,3-diol mol­ecule is generated by crystallographic twofold symmetry and two O—H⋯O hydrogen bonds are formed with the uncoordinated O atoms of the sulfate group.
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spelling pubmed-29791852010-12-30 Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κ(2) O,O′)zinc(II) propane-1,3-diol solvate Cui, Jiang-Dong Zhong, Kai-Long Liu, Yan-Yun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(SO(4))(C(12)H(8)N(2))(2)]·C(3)H(8)O(2), the Zn(2+) ion (site symmetry 2) is coordinated by two chelating 1,10-phenanthroline ligands and an O,O′-bidentate sulfate ion (S site symmetry 2), resulting in a distorted cis-ZnO(2)N(4) octa­hedral geometry for the metal ion. The complete propane-1,3-diol mol­ecule is generated by crystallographic twofold symmetry and two O—H⋯O hydrogen bonds are formed with the uncoordinated O atoms of the sulfate group. International Union of Crystallography 2010-04-24 /pmc/articles/PMC2979185/ /pubmed/21579046 http://dx.doi.org/10.1107/S1600536810014194 Text en © Cui et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Cui, Jiang-Dong
Zhong, Kai-Long
Liu, Yan-Yun
Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κ(2) O,O′)zinc(II) propane-1,3-diol solvate
title Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κ(2) O,O′)zinc(II) propane-1,3-diol solvate
title_full Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κ(2) O,O′)zinc(II) propane-1,3-diol solvate
title_fullStr Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κ(2) O,O′)zinc(II) propane-1,3-diol solvate
title_full_unstemmed Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κ(2) O,O′)zinc(II) propane-1,3-diol solvate
title_short Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κ(2) O,O′)zinc(II) propane-1,3-diol solvate
title_sort bis(1,10-phenanthroline-κ(2) n,n′)(sulfato-κ(2) o,o′)zinc(ii) propane-1,3-diol solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979185/
https://www.ncbi.nlm.nih.gov/pubmed/21579046
http://dx.doi.org/10.1107/S1600536810014194
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AT zhongkailong bis110phenanthrolinek2nnsulfatok2oozinciipropane13diolsolvate
AT liuyanyun bis110phenanthrolinek2nnsulfatok2oozinciipropane13diolsolvate

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