Bis(μ-phenyl­tellurido-κ(2) Te:Te)bis­[tetra­carbonyl­rhenium(I)]

The title compound, [Re(2)(C(6)H(5)Te)(2)(CO)(8)], crystallizes with two mol­ecules in the asymmetric unit, in which two Re atoms are coordinated in a slightly distorted octa­hedral environment and are bridged by two Te atoms, which show a distorted trigonal-pyramidal geometry. The torsion angles fo...

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Autores principales: Muthukumaran, J., Kannan, M., Vanitha, A., Manimaran, Bala, Krishna, R.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979195/
https://www.ncbi.nlm.nih.gov/pubmed/21579041
http://dx.doi.org/10.1107/S1600536810014297
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author Muthukumaran, J.
Kannan, M.
Vanitha, A.
Manimaran, Bala
Krishna, R.
author_facet Muthukumaran, J.
Kannan, M.
Vanitha, A.
Manimaran, Bala
Krishna, R.
author_sort Muthukumaran, J.
collection PubMed
description The title compound, [Re(2)(C(6)H(5)Te)(2)(CO)(8)], crystallizes with two mol­ecules in the asymmetric unit, in which two Re atoms are coordinated in a slightly distorted octa­hedral environment and are bridged by two Te atoms, which show a distorted trigonal-pyramidal geometry. The torsion angles for the Te—Re—Te—Re sequence of atoms are 19.29 (18) and 16.54 (16)° in the two mol­ecules. Thus, the Re—Te four-membered rings in the two mol­ecules deviate significantly from planarity. Two intra­molecular C—H⋯O inter­actions occur in one of the mol­ecules. Te—Te [4.0551 (10) Å] inter­actions between the two mol­ecules and weak inter­molecular C—H⋯O inter­actions stabilize the crystal packing.
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spelling pubmed-29791952010-12-30 Bis(μ-phenyl­tellurido-κ(2) Te:Te)bis­[tetra­carbonyl­rhenium(I)] Muthukumaran, J. Kannan, M. Vanitha, A. Manimaran, Bala Krishna, R. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Re(2)(C(6)H(5)Te)(2)(CO)(8)], crystallizes with two mol­ecules in the asymmetric unit, in which two Re atoms are coordinated in a slightly distorted octa­hedral environment and are bridged by two Te atoms, which show a distorted trigonal-pyramidal geometry. The torsion angles for the Te—Re—Te—Re sequence of atoms are 19.29 (18) and 16.54 (16)° in the two mol­ecules. Thus, the Re—Te four-membered rings in the two mol­ecules deviate significantly from planarity. Two intra­molecular C—H⋯O inter­actions occur in one of the mol­ecules. Te—Te [4.0551 (10) Å] inter­actions between the two mol­ecules and weak inter­molecular C—H⋯O inter­actions stabilize the crystal packing. International Union of Crystallography 2010-04-24 /pmc/articles/PMC2979195/ /pubmed/21579041 http://dx.doi.org/10.1107/S1600536810014297 Text en © Muthukumaran et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Muthukumaran, J.
Kannan, M.
Vanitha, A.
Manimaran, Bala
Krishna, R.
Bis(μ-phenyl­tellurido-κ(2) Te:Te)bis­[tetra­carbonyl­rhenium(I)]
title Bis(μ-phenyl­tellurido-κ(2) Te:Te)bis­[tetra­carbonyl­rhenium(I)]
title_full Bis(μ-phenyl­tellurido-κ(2) Te:Te)bis­[tetra­carbonyl­rhenium(I)]
title_fullStr Bis(μ-phenyl­tellurido-κ(2) Te:Te)bis­[tetra­carbonyl­rhenium(I)]
title_full_unstemmed Bis(μ-phenyl­tellurido-κ(2) Te:Te)bis­[tetra­carbonyl­rhenium(I)]
title_short Bis(μ-phenyl­tellurido-κ(2) Te:Te)bis­[tetra­carbonyl­rhenium(I)]
title_sort bis(μ-phenyl­tellurido-κ(2) te:te)bis­[tetra­carbonyl­rhenium(i)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979195/
https://www.ncbi.nlm.nih.gov/pubmed/21579041
http://dx.doi.org/10.1107/S1600536810014297
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AT manimaranbala bismphenyltelluridok2tetebistetracarbonylrheniumi
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