2-(4-Chloro­benzo­yl)-1-(diamino­methyl­ene)hydrazinium chloride monohydrate

In the cation of the title compound, C(8)H(10)ClN(4)O(+)·Cl(−)·H(2)O, the guanidinium group is planar (maximum deviation = 0.0001 Å) and nearly perpendicular to carboxamide group, making a dihedral angle of 87.0 (3)°. The N atoms of the guanidine fragment have a planar trigonal configuration and the...

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Detalles Bibliográficos
Autores principales: Chernyshev, V. M., Chernysheva, A. V., Tarasova, E. V., Ivanov, V. V., Starikova, Z. A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979199/
https://www.ncbi.nlm.nih.gov/pubmed/21579199
http://dx.doi.org/10.1107/S1600536810014108
Descripción
Sumario:In the cation of the title compound, C(8)H(10)ClN(4)O(+)·Cl(−)·H(2)O, the guanidinium group is planar (maximum deviation = 0.0001 Å) and nearly perpendicular to carboxamide group, making a dihedral angle of 87.0 (3)°. The N atoms of the guanidine fragment have a planar trigonal configuration and the N atom of the carboxamide group adopts a pyramidal configuration. In the crystal structure, inter­molecular N—H⋯O, N—H⋯Cl and O—H⋯Cl hydrogen bonds link the cations, anions and water mol­ecules into layers parallel to the bc plane.

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