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Diaquabis(4-methylbenzoato-κO)bis(nicotinamide-κN (1))manganese(II)
In the mononuclear title complex, [Mn(C(8)H(7)O(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the Mn(II) ion is located on a crystallographic inversion center. The asymmetric unit contains one 4-methylbenzoate anion, one nicotinamide (NA) ligand and one coordinated water molecule. The four O atoms in the e...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979200/ https://www.ncbi.nlm.nih.gov/pubmed/21578994 http://dx.doi.org/10.1107/S1600536810011815 |
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author | Necefoğlu, Hacali Çimen, Efdal Tercan, Barış Dal, Hakan Hökelek, Tuncer |
author_facet | Necefoğlu, Hacali Çimen, Efdal Tercan, Barış Dal, Hakan Hökelek, Tuncer |
author_sort | Necefoğlu, Hacali |
collection | PubMed |
description | In the mononuclear title complex, [Mn(C(8)H(7)O(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the Mn(II) ion is located on a crystallographic inversion center. The asymmetric unit contains one 4-methylbenzoate anion, one nicotinamide (NA) ligand and one coordinated water molecule. The four O atoms in the equatorial plane around the Mn(II) ion form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two pyridine N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxylate group and the attached benzene ring is 9.01 (7)°, while the pyridine and benzene rings are oriented at a dihedral angle of 42.44 (5)°. In the crystal structure, intermolecular O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds, and O—H⋯π and C—H⋯π interactions link the molecules into a two-dimensional network parallel to (001). |
format | Text |
id | pubmed-2979200 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29792002010-12-30 Diaquabis(4-methylbenzoato-κO)bis(nicotinamide-κN (1))manganese(II) Necefoğlu, Hacali Çimen, Efdal Tercan, Barış Dal, Hakan Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mononuclear title complex, [Mn(C(8)H(7)O(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the Mn(II) ion is located on a crystallographic inversion center. The asymmetric unit contains one 4-methylbenzoate anion, one nicotinamide (NA) ligand and one coordinated water molecule. The four O atoms in the equatorial plane around the Mn(II) ion form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two pyridine N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxylate group and the attached benzene ring is 9.01 (7)°, while the pyridine and benzene rings are oriented at a dihedral angle of 42.44 (5)°. In the crystal structure, intermolecular O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds, and O—H⋯π and C—H⋯π interactions link the molecules into a two-dimensional network parallel to (001). International Union of Crystallography 2010-04-10 /pmc/articles/PMC2979200/ /pubmed/21578994 http://dx.doi.org/10.1107/S1600536810011815 Text en © Necefoğlu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Necefoğlu, Hacali Çimen, Efdal Tercan, Barış Dal, Hakan Hökelek, Tuncer Diaquabis(4-methylbenzoato-κO)bis(nicotinamide-κN (1))manganese(II) |
title | Diaquabis(4-methylbenzoato-κO)bis(nicotinamide-κN
(1))manganese(II) |
title_full | Diaquabis(4-methylbenzoato-κO)bis(nicotinamide-κN
(1))manganese(II) |
title_fullStr | Diaquabis(4-methylbenzoato-κO)bis(nicotinamide-κN
(1))manganese(II) |
title_full_unstemmed | Diaquabis(4-methylbenzoato-κO)bis(nicotinamide-κN
(1))manganese(II) |
title_short | Diaquabis(4-methylbenzoato-κO)bis(nicotinamide-κN
(1))manganese(II) |
title_sort | diaquabis(4-methylbenzoato-κo)bis(nicotinamide-κn
(1))manganese(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979200/ https://www.ncbi.nlm.nih.gov/pubmed/21578994 http://dx.doi.org/10.1107/S1600536810011815 |
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