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Diaqua­bis(4-methyl­benzoato-κO)bis­(nicotinamide-κN (1))manganese(II)

In the mononuclear title complex, [Mn(C(8)H(7)O(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the Mn(II) ion is located on a crystallographic inversion center. The asymmetric unit contains one 4-methyl­benzoate anion, one nicotinamide (NA) ligand and one coordinated water mol­ecule. The four O atoms in the e...

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Autores principales: Necefoğlu, Hacali, Çimen, Efdal, Tercan, Barış, Dal, Hakan, Hökelek, Tuncer
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979200/
https://www.ncbi.nlm.nih.gov/pubmed/21578994
http://dx.doi.org/10.1107/S1600536810011815
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author Necefoğlu, Hacali
Çimen, Efdal
Tercan, Barış
Dal, Hakan
Hökelek, Tuncer
author_facet Necefoğlu, Hacali
Çimen, Efdal
Tercan, Barış
Dal, Hakan
Hökelek, Tuncer
author_sort Necefoğlu, Hacali
collection PubMed
description In the mononuclear title complex, [Mn(C(8)H(7)O(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the Mn(II) ion is located on a crystallographic inversion center. The asymmetric unit contains one 4-methyl­benzoate anion, one nicotinamide (NA) ligand and one coordinated water mol­ecule. The four O atoms in the equatorial plane around the Mn(II) ion form a slightly distorted square-planar arrangement, while the slightly distorted octa­hedral coordination is completed by the two pyridine N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxyl­ate group and the attached benzene ring is 9.01 (7)°, while the pyridine and benzene rings are oriented at a dihedral angle of 42.44 (5)°. In the crystal structure, inter­molecular O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds, and O—H⋯π and C—H⋯π inter­actions link the mol­ecules into a two-dimensional network parallel to (001).
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spelling pubmed-29792002010-12-30 Diaqua­bis(4-methyl­benzoato-κO)bis­(nicotinamide-κN (1))manganese(II) Necefoğlu, Hacali Çimen, Efdal Tercan, Barış Dal, Hakan Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mononuclear title complex, [Mn(C(8)H(7)O(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the Mn(II) ion is located on a crystallographic inversion center. The asymmetric unit contains one 4-methyl­benzoate anion, one nicotinamide (NA) ligand and one coordinated water mol­ecule. The four O atoms in the equatorial plane around the Mn(II) ion form a slightly distorted square-planar arrangement, while the slightly distorted octa­hedral coordination is completed by the two pyridine N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxyl­ate group and the attached benzene ring is 9.01 (7)°, while the pyridine and benzene rings are oriented at a dihedral angle of 42.44 (5)°. In the crystal structure, inter­molecular O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds, and O—H⋯π and C—H⋯π inter­actions link the mol­ecules into a two-dimensional network parallel to (001). International Union of Crystallography 2010-04-10 /pmc/articles/PMC2979200/ /pubmed/21578994 http://dx.doi.org/10.1107/S1600536810011815 Text en © Necefoğlu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Necefoğlu, Hacali
Çimen, Efdal
Tercan, Barış
Dal, Hakan
Hökelek, Tuncer
Diaqua­bis(4-methyl­benzoato-κO)bis­(nicotinamide-κN (1))manganese(II)
title Diaqua­bis(4-methyl­benzoato-κO)bis­(nicotinamide-κN (1))manganese(II)
title_full Diaqua­bis(4-methyl­benzoato-κO)bis­(nicotinamide-κN (1))manganese(II)
title_fullStr Diaqua­bis(4-methyl­benzoato-κO)bis­(nicotinamide-κN (1))manganese(II)
title_full_unstemmed Diaqua­bis(4-methyl­benzoato-κO)bis­(nicotinamide-κN (1))manganese(II)
title_short Diaqua­bis(4-methyl­benzoato-κO)bis­(nicotinamide-κN (1))manganese(II)
title_sort diaqua­bis(4-methyl­benzoato-κo)bis­(nicotinamide-κn (1))manganese(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979200/
https://www.ncbi.nlm.nih.gov/pubmed/21578994
http://dx.doi.org/10.1107/S1600536810011815
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